Anti-ASF distribution in Fischer-Tropsch synthesis over unsupported cobalt catalysts in a batch slurry phase reactor

Fischer-Tropsch synthesis (FTS) over unsupported coprecipitated cobalt catalysts in n-decane in a batch slurry phase reactor by adding water vapor (H₂O/CO=0.12 in molar ratio) prior to reaction has been studied. The addition of water vapor exhibits a marked effect on the product selectivity. In the absence of water, the carbon number distribution of FT products follows the classical Anderson-Schulz-Flory (ASF) pattern resulting in a low selectivity (32%) in the desired C₁₀+ hydrocarbons. In contrast, with the promotion of water vapor, the formation of heavy products is appreciably increased up to 87.3% in C₁₀+ hydrocarbons so that the selectivity in the range of C₈-C₃₀ increases obviously along with an increase in carbon number (n), which leads to a substantial deviation from ASF pattern. The effect of water is explained by suppressing secondary hydrogenation of 1-olefins and facilitating their readsorption and chain growth.