Application of a Mixed Oxide Capacitor to the Selective Carbon Dioxide Sensor II. CO2 Sensing Characteristics of a Cuo-Based Oxide Capacitor

Tatsumi ishihara, Kazuhiro Kometani, Yukako Mizuhara, Yusaku Takita

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Characteristics for CO2 sensing of a CuO-based oxide capacitor were studied. The capacitances of CuO mixed with BaSnO3 SrTiO3, CaTiO3, and ZnO are dependent on the CO2 concentration, similar to CuO-BaTiO2. In particular, the mixed oxide, CuO-SrTiO3, is more sensitive to CO2 than CuO-BaTiO3, but requires a rather long time to recover. On the other hand, the mixed oxide capacitor, CuO-BaSnO3, exhibits high CO2 sensitivity, and a monotonic and approximately logarithmic relationship exists between the sensitivity and the concentration of CO2 from 100 ppm to 50%. Furthermore, the capacitance of CuO-BaSnO3 increased rapidly within 30s after exposure to 2% CO2, and returned rapidly to the original level after reexposure to air. Therefore, the system, CuO-BaSnO3 is promising for sensing CO2 over a wide range of concentrations. From a complex impedance measurement, the equivalent circuit of the sensor element can be expressed by a series connection of three parallel resistors and capacitors which correspond to the intragrain region, grain interface between CuO and BaSnO3, and electrode interface. Since exposure of the element to 2% CO2 varied the capacitance of the grain interface, the grain interface between CuO and BaSnOa has an important role for CO2 detection.

Original languageEnglish
Pages (from-to)2881-2885
Number of pages5
JournalJournal of the Electrochemical Society
Volume139
Issue number10
DOIs
Publication statusPublished - Jan 1 1992
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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