Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells

Yu Ming Chen, Tai Nan Lin, Ming Wei Liao, Hong Yi Kuo, Chun Yen Yeh, Wei Xin Kao, Sheng Fu Yang, Kuan Ting Wu, Tatsumi Ishihara

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Solid oxide fuel cells (SOFCs) are recognized as environmentally friendly, highly efficient devices, and alternatives to conventional energy conversion systems. Typical material design used is the YSZ-based cell consisting of NiO-YSZ and LSM as anode and cathode, with a dense electrolyte of YSZ. When considering the use of hydrocarbon fuels, carbon deposition has been observed as major failure issue in electrodes. Also the homogeneity of the electrolyte is essential for the gas-tightness after sintering process. In this article, we propose an innovative chemical reactor with powder collection system and its application to glycine-nitrate combustion process to produce precision ceramic powder in nano scale; it not only generates precision ceramic powder of specific chemical composition on a mass-production scale, but also the system has the primary features of withstanding the instant hightemperature flare and pressure during powder formation reaction. Electrodes/electrolyte powders, SmBa0.5Sr0.5Co2O5+δ (SBSC), Ce0.6Mn0.3Fe0.1O2 (CMF), and La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM), have been synthesized and characterized for the crystallinity, microstructure, conductivity, coefficient of thermal expansion properties were studied. The material application to form an SOFC has been executed and cell performances are investigated as well.

Original languageEnglish
Title of host publicationECS Transactions
EditorsT. Kawada, S. C. Singhal
PublisherElectrochemical Society Inc.
Pages773-781
Number of pages9
Edition1
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - May 30 2017
Event15th International Symposium on Solid Oxide Fuel Cells, SOFC 2017 - Hollywood, United States
Duration: Jul 23 2017Jul 28 2017

Publication series

NameECS Transactions
Number1
Volume78
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Other

Other15th International Symposium on Solid Oxide Fuel Cells, SOFC 2017
CountryUnited States
CityHollywood
Period7/23/177/28/17

Fingerprint

Solid oxide fuel cells (SOFC)
Amino acids
Nitrates
Electrolytes
Powders
Chemical reactors
Electrodes
Energy conversion
Thermal expansion
Anodes
Cathodes
Sintering
Hydrocarbons
Microstructure
Carbon
Chemical analysis
Gases

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Chen, Y. M., Lin, T. N., Liao, M. W., Kuo, H. Y., Yeh, C. Y., Kao, W. X., ... Ishihara, T. (2017). Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells. In T. Kawada, & S. C. Singhal (Eds.), ECS Transactions (1 ed., pp. 773-781). (ECS Transactions; Vol. 78, No. 1). Electrochemical Society Inc.. https://doi.org/10.1149/07801.0773ecst

Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells. / Chen, Yu Ming; Lin, Tai Nan; Liao, Ming Wei; Kuo, Hong Yi; Yeh, Chun Yen; Kao, Wei Xin; Yang, Sheng Fu; Wu, Kuan Ting; Ishihara, Tatsumi.

ECS Transactions. ed. / T. Kawada; S. C. Singhal. 1. ed. Electrochemical Society Inc., 2017. p. 773-781 (ECS Transactions; Vol. 78, No. 1).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Chen, YM, Lin, TN, Liao, MW, Kuo, HY, Yeh, CY, Kao, WX, Yang, SF, Wu, KT & Ishihara, T 2017, Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells. in T Kawada & SC Singhal (eds), ECS Transactions. 1 edn, ECS Transactions, no. 1, vol. 78, Electrochemical Society Inc., pp. 773-781, 15th International Symposium on Solid Oxide Fuel Cells, SOFC 2017, Hollywood, United States, 7/23/17. https://doi.org/10.1149/07801.0773ecst
Chen YM, Lin TN, Liao MW, Kuo HY, Yeh CY, Kao WX et al. Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells. In Kawada T, Singhal SC, editors, ECS Transactions. 1 ed. Electrochemical Society Inc. 2017. p. 773-781. (ECS Transactions; 1). https://doi.org/10.1149/07801.0773ecst
Chen, Yu Ming ; Lin, Tai Nan ; Liao, Ming Wei ; Kuo, Hong Yi ; Yeh, Chun Yen ; Kao, Wei Xin ; Yang, Sheng Fu ; Wu, Kuan Ting ; Ishihara, Tatsumi. / Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells. ECS Transactions. editor / T. Kawada ; S. C. Singhal. 1. ed. Electrochemical Society Inc., 2017. pp. 773-781 (ECS Transactions; 1).
@inproceedings{6f59804b15414fe69abd1df627a8926b,
title = "Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells",
abstract = "Solid oxide fuel cells (SOFCs) are recognized as environmentally friendly, highly efficient devices, and alternatives to conventional energy conversion systems. Typical material design used is the YSZ-based cell consisting of NiO-YSZ and LSM as anode and cathode, with a dense electrolyte of YSZ. When considering the use of hydrocarbon fuels, carbon deposition has been observed as major failure issue in electrodes. Also the homogeneity of the electrolyte is essential for the gas-tightness after sintering process. In this article, we propose an innovative chemical reactor with powder collection system and its application to glycine-nitrate combustion process to produce precision ceramic powder in nano scale; it not only generates precision ceramic powder of specific chemical composition on a mass-production scale, but also the system has the primary features of withstanding the instant hightemperature flare and pressure during powder formation reaction. Electrodes/electrolyte powders, SmBa0.5Sr0.5Co2O5+δ (SBSC), Ce0.6Mn0.3Fe0.1O2 (CMF), and La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM), have been synthesized and characterized for the crystallinity, microstructure, conductivity, coefficient of thermal expansion properties were studied. The material application to form an SOFC has been executed and cell performances are investigated as well.",
author = "Chen, {Yu Ming} and Lin, {Tai Nan} and Liao, {Ming Wei} and Kuo, {Hong Yi} and Yeh, {Chun Yen} and Kao, {Wei Xin} and Yang, {Sheng Fu} and Wu, {Kuan Ting} and Tatsumi Ishihara",
year = "2017",
month = "5",
day = "30",
doi = "10.1149/07801.0773ecst",
language = "English",
series = "ECS Transactions",
publisher = "Electrochemical Society Inc.",
number = "1",
pages = "773--781",
editor = "T. Kawada and Singhal, {S. C.}",
booktitle = "ECS Transactions",
edition = "1",

}

TY - GEN

T1 - Applications of the glycine nitrate combustion method for powder synthesis on the LSGM-based electrolyte-supported solid oxide fuel cells

AU - Chen, Yu Ming

AU - Lin, Tai Nan

AU - Liao, Ming Wei

AU - Kuo, Hong Yi

AU - Yeh, Chun Yen

AU - Kao, Wei Xin

AU - Yang, Sheng Fu

AU - Wu, Kuan Ting

AU - Ishihara, Tatsumi

PY - 2017/5/30

Y1 - 2017/5/30

N2 - Solid oxide fuel cells (SOFCs) are recognized as environmentally friendly, highly efficient devices, and alternatives to conventional energy conversion systems. Typical material design used is the YSZ-based cell consisting of NiO-YSZ and LSM as anode and cathode, with a dense electrolyte of YSZ. When considering the use of hydrocarbon fuels, carbon deposition has been observed as major failure issue in electrodes. Also the homogeneity of the electrolyte is essential for the gas-tightness after sintering process. In this article, we propose an innovative chemical reactor with powder collection system and its application to glycine-nitrate combustion process to produce precision ceramic powder in nano scale; it not only generates precision ceramic powder of specific chemical composition on a mass-production scale, but also the system has the primary features of withstanding the instant hightemperature flare and pressure during powder formation reaction. Electrodes/electrolyte powders, SmBa0.5Sr0.5Co2O5+δ (SBSC), Ce0.6Mn0.3Fe0.1O2 (CMF), and La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM), have been synthesized and characterized for the crystallinity, microstructure, conductivity, coefficient of thermal expansion properties were studied. The material application to form an SOFC has been executed and cell performances are investigated as well.

AB - Solid oxide fuel cells (SOFCs) are recognized as environmentally friendly, highly efficient devices, and alternatives to conventional energy conversion systems. Typical material design used is the YSZ-based cell consisting of NiO-YSZ and LSM as anode and cathode, with a dense electrolyte of YSZ. When considering the use of hydrocarbon fuels, carbon deposition has been observed as major failure issue in electrodes. Also the homogeneity of the electrolyte is essential for the gas-tightness after sintering process. In this article, we propose an innovative chemical reactor with powder collection system and its application to glycine-nitrate combustion process to produce precision ceramic powder in nano scale; it not only generates precision ceramic powder of specific chemical composition on a mass-production scale, but also the system has the primary features of withstanding the instant hightemperature flare and pressure during powder formation reaction. Electrodes/electrolyte powders, SmBa0.5Sr0.5Co2O5+δ (SBSC), Ce0.6Mn0.3Fe0.1O2 (CMF), and La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM), have been synthesized and characterized for the crystallinity, microstructure, conductivity, coefficient of thermal expansion properties were studied. The material application to form an SOFC has been executed and cell performances are investigated as well.

UR - http://www.scopus.com/inward/record.url?scp=85028452595&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85028452595&partnerID=8YFLogxK

U2 - 10.1149/07801.0773ecst

DO - 10.1149/07801.0773ecst

M3 - Conference contribution

AN - SCOPUS:85028452595

T3 - ECS Transactions

SP - 773

EP - 781

BT - ECS Transactions

A2 - Kawada, T.

A2 - Singhal, S. C.

PB - Electrochemical Society Inc.

ER -