Approach to Superlattice of Transition Metal Coordination Compounds by Selective Coordinating Epitaxy

Kazuhiro Takahashi, Hiroshi Tanino, Takafumi Yao

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Abstract

A double heterostructure of transition metal coordination compounds (TMCC), [Pt<SUP>II</SUP>(en)<SUB>2</SUB>][Pt<SUP>IV</SUP>X<SUB>2</SUB>(en)<SUB>2</SUB>]Y<SUB>4</SUB>(abbreviated as 'X'), where en=1,2-diaminoethane, X=Cl, Br, Y=ClO<SUB>4</SUB> or BF<SUB>4</SUB>, is grown by selective coordination epitaxy (SCE) for the first time. The fact indicates that superlattice of TMCC can be realized by SCE. A heterostructure including the mixed-crystal 'Cl<SUB>1−<I>x</I></SUB>Br<I><SUB>x</SUB></I>' (Y=ClO<SUB>4</SUB>) is also reported. The band structure of the superlattice of TMCC's can be controlled continuously in the same manner as that of GaAs/Al<SUB>1−<I>x</I></SUB>Ga<I><SUB>x</SUB></I>As/AlAs superlattice and reference is made to the polarized reflectance spectra of the mixed-crystals.
Original languageEnglish
Pages (from-to)L97-L99
JournalJapanese Journal of Applied Physics, Part 2: Letters
Volume26
Issue number2
Publication statusPublished - 1987

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Chemistry(all)

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