Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide

Yaohiro Inagaki, Toshitaka Imamura, Kazuya Idemitsu, Tatsumi Arima, Osamu Kato, Hidekazu Asano, Tsutomu Nishimura

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

Aqueous dissolution tests of silver iodide (AgI) were performed in Na 2S solutions in order to evaluate, empirically, dissolution of AgI to release iodine under reducing conditions with sulfide. The results indicated that AgI dissolves to release iodine being controlled by mainly precipitation of Ag2S. However, the dissolution of AgI can be depressed to proceed, and the thermodynamic equihbrium cannot be attained easily. Solid phase analysis for the reacted AgI suggested that a thin layer of solid silver forming at AgI surface may evolve to be protective against transportation of reactant species, which can lead to the depression in the dissolution of AgI.

Original languageEnglish
Title of host publicationScientific Basis for Nuclear Waste Management XXX
Pages431-436
Number of pages6
Publication statusPublished - Dec 1 2007
Event2006 MRS Fall Meeting - Boston, MA, United States
Duration: Nov 27 2006Dec 1 2006

Publication series

NameMaterials Research Society Symposium Proceedings
Volume985
ISSN (Print)0272-9172

Other

Other2006 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period11/27/0612/1/06

Fingerprint

silver iodides
Sulfides
Iodine
iodine
sulfides
dissolving
Dissolution
Silver
solid phases
silver
Thermodynamics
thermodynamics
silver iodide

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Inagaki, Y., Imamura, T., Idemitsu, K., Arima, T., Kato, O., Asano, H., & Nishimura, T. (2007). Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide. In Scientific Basis for Nuclear Waste Management XXX (pp. 431-436). (Materials Research Society Symposium Proceedings; Vol. 985).

Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide. / Inagaki, Yaohiro; Imamura, Toshitaka; Idemitsu, Kazuya; Arima, Tatsumi; Kato, Osamu; Asano, Hidekazu; Nishimura, Tsutomu.

Scientific Basis for Nuclear Waste Management XXX. 2007. p. 431-436 (Materials Research Society Symposium Proceedings; Vol. 985).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Inagaki, Y, Imamura, T, Idemitsu, K, Arima, T, Kato, O, Asano, H & Nishimura, T 2007, Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide. in Scientific Basis for Nuclear Waste Management XXX. Materials Research Society Symposium Proceedings, vol. 985, pp. 431-436, 2006 MRS Fall Meeting, Boston, MA, United States, 11/27/06.
Inagaki Y, Imamura T, Idemitsu K, Arima T, Kato O, Asano H et al. Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide. In Scientific Basis for Nuclear Waste Management XXX. 2007. p. 431-436. (Materials Research Society Symposium Proceedings).
Inagaki, Yaohiro ; Imamura, Toshitaka ; Idemitsu, Kazuya ; Arima, Tatsumi ; Kato, Osamu ; Asano, Hidekazu ; Nishimura, Tsutomu. / Aqueous dissolution of silver iodide and associated iodine release under reducing conditions with sulfide. Scientific Basis for Nuclear Waste Management XXX. 2007. pp. 431-436 (Materials Research Society Symposium Proceedings).
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