Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer

Hui Zhong Kou, Jun Tao, Osamu Sato

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Abstract

Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

Original languageEnglish
Pages (from-to)3652-3656
Number of pages5
JournalDalton Transactions
Issue number28
DOIs
Publication statusPublished - Jul 16 2008

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All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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