Asymmetric [2,3]-Wittig Rearrangement Approach to the Formal Synthesis of (+)-Brefeldin A

Katsuhiko Tomooka; Katsuya Ishikawa; Takeshi Nakai

doi:10.1055/s-1995-5152

Asymmetric [2,3]-Wittig Rearrangement Approach to the Formal Synthesis of (+)-Brefeldin A

Katsuhiko Tomooka, Katsuya Ishikawa, Takeshi Nakai

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

An asymmetric synthesis of the 2,4-disubstituted 1-cyclopentanal, a key precursor of brefeldin A, is described which involves as the key step an asymmetric [2,3]-Wittig rearrangement to control both the ring and side chain configurations.

Original language	English
Pages (from-to)	901-902
Number of pages	2
Journal	Synlett
Volume	1995
Issue number	9
DOIs	https://doi.org/10.1055/s-1995-5152
Publication status	Published - Sept 1 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-1995-5152

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title = "Asymmetric [2,3]-Wittig Rearrangement Approach to the Formal Synthesis of (+)-Brefeldin A",

abstract = "An asymmetric synthesis of the 2,4-disubstituted 1-cyclopentanal, a key precursor of brefeldin A, is described which involves as the key step an asymmetric [2,3]-Wittig rearrangement to control both the ring and side chain configurations.",

author = "Katsuhiko Tomooka and Katsuya Ishikawa and Takeshi Nakai",

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AU - Tomooka, Katsuhiko

AU - Ishikawa, Katsuya

AU - Nakai, Takeshi

PY - 1995/9/1

Y1 - 1995/9/1

N2 - An asymmetric synthesis of the 2,4-disubstituted 1-cyclopentanal, a key precursor of brefeldin A, is described which involves as the key step an asymmetric [2,3]-Wittig rearrangement to control both the ring and side chain configurations.

AB - An asymmetric synthesis of the 2,4-disubstituted 1-cyclopentanal, a key precursor of brefeldin A, is described which involves as the key step an asymmetric [2,3]-Wittig rearrangement to control both the ring and side chain configurations.

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U2 - 10.1055/s-1995-5152

DO - 10.1055/s-1995-5152

M3 - Article

AN - SCOPUS:1542632043

SN - 0936-5214

VL - 1995

SP - 901

EP - 902

JO - Synlett

JF - Synlett

IS - 9

ER -

Asymmetric [2,3]-Wittig Rearrangement Approach to the Formal Synthesis of (+)-Brefeldin A

Abstract

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