Asymmetric aldol reaction of 2-cyanopropionates catalysed by trans-chelating chiral diphosphine ligand TRAP-rhodium(I) complex

Ryoichi Kuwano, Hiroshi Miyazaki, Yoshihiko Ito

Research output: Contribution to journalArticle

78 Citations (Scopus)

Abstract

trans-Chelating chiral diphosphine TRAP ligands bearing P-aromatic groups are effective for RhI-catalysed asymmetric aldol reaction of 2-cyanopropionates with an aldehyde to give the corresponding aldol adduct with up to 93% ee.

Original languageEnglish
Pages (from-to)71-72
Number of pages2
JournalChemical Communications
Issue number1
DOIs
Publication statusPublished - Jan 7 1998
Externally publishedYes

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Bearings (structural)
Rhodium
Chelation
Aldehydes
Ligands
3-hydroxybutanal

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Asymmetric aldol reaction of 2-cyanopropionates catalysed by trans-chelating chiral diphosphine ligand TRAP-rhodium(I) complex. / Kuwano, Ryoichi; Miyazaki, Hiroshi; Ito, Yoshihiko.

In: Chemical Communications, No. 1, 07.01.1998, p. 71-72.

Research output: Contribution to journalArticle

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