Asymmetric Carroll rearrangement of allyl α-acetamido-β- ketocarboxylates catalysed by a chiral palladium complex

Ryoichi Kuwano, Naoki Ishida, Masahiro Murakami

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Asymmetric decarboxylative rearrangement (Carroll rearrangement) of allyl α-acetamido-β-ketocarboxylates was catalysed by a palladium complex modified with a chiral phosphine ligand, giving optically active γ,δ-unsaturated α-aminoketones with up to 90% ee.

Original languageEnglish
Pages (from-to)3951-3952
Number of pages2
JournalChemical Communications
Issue number31
DOIs
Publication statusPublished - Aug 21 2005

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phosphine
Palladium
Ligands

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Asymmetric Carroll rearrangement of allyl α-acetamido-β- ketocarboxylates catalysed by a chiral palladium complex. / Kuwano, Ryoichi; Ishida, Naoki; Murakami, Masahiro.

In: Chemical Communications, No. 31, 21.08.2005, p. 3951-3952.

Research output: Contribution to journalArticle

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