Abstract
Asymmetric decarboxylative rearrangement (Carroll rearrangement) of allyl α-acetamido-β-ketocarboxylates was catalysed by a palladium complex modified with a chiral phosphine ligand, giving optically active γ,δ-unsaturated α-aminoketones with up to 90% ee.
| Original language | English |
|---|---|
| Pages (from-to) | 3951-3952 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Issue number | 31 |
| DOIs | |
| Publication status | Published - Aug 21 2005 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry