Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Masahiro Hirama; Tohru Oishi; Shô Itô

doi:10.1039/C39890000665

Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Masahiro Hirama, Tohru Oishi, Shô Itô

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

Original language	English
Pages (from-to)	665-666
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39890000665
Publication status	Published - Jan 1 1989
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

Access to Document

10.1039/C39890000665

Cite this

@article{9b6cf1fedbd8481c9d398f1b86e51454,

title = "Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex",

abstract = "Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.",

author = "Masahiro Hirama and Tohru Oishi and Sh{\^o} It{\^o}",

year = "1989",

month = jan,

day = "1",

doi = "10.1039/C39890000665",

language = "English",

pages = "665--666",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Asymmetric dihydroxylation of alkenes with osmium tetroxide

T2 - Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

AU - Hirama, Masahiro

AU - Oishi, Tohru

AU - Itô, Shô

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

AB - Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

UR - http://www.scopus.com/inward/record.url?scp=37049067929&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049067929&partnerID=8YFLogxK

U2 - 10.1039/C39890000665

DO - 10.1039/C39890000665

M3 - Article

AN - SCOPUS:37049067929

SP - 665

EP - 666

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 10

ER -

Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this