Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Masahiro Hirama; Tohru Oishi; Shô Itô

doi:10.1039/C39890000665

Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Masahiro Hirama, Tohru Oishi, Shô Itô

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Abstract

Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

Original language	English
Pages (from-to)	665-666
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39890000665
Publication status	Published - Jan 1 1989
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex",

abstract = "Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.",

author = "Masahiro Hirama and Tohru Oishi and Sh{\^o} It{\^o}",

year = "1989",

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doi = "10.1039/C39890000665",

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AU - Hirama, Masahiro

AU - Oishi, Tohru

AU - Itô, Shô

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N2 - Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

AB - Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

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Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Abstract

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