Asymmetric dihydroxylation of alkenes with osmium tetroxide: Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

Masahiro Hirama, Tohru Oishi, Shô Itô

Research output: Contribution to journalArticle

77 Citations (Scopus)

Abstract

Asymmetric osmylation of alkenes by using N,N′-dialkyl-2,2′- bipyrrolidines as the chiral ligands shows a high asymmetric induction and a marked dependence of the enantioselectivity on both the N-alkyl group and the reaction solvent.

Original languageEnglish
Pages (from-to)665-666
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number10
DOIs
Publication statusPublished - Jan 1 1989
Externally publishedYes

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Osmium Tetroxide
Osmium
Enantioselectivity
Alkenes
Olefins
Ligands

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

Asymmetric dihydroxylation of alkenes with osmium tetroxide : Chiral N,N′-dialkyl-2,2′-bipyrrolidine complex. / Hirama, Masahiro; Oishi, Tohru; Itô, Shô.

In: Journal of the Chemical Society, Chemical Communications, No. 10, 01.01.1989, p. 665-666.

Research output: Contribution to journalArticle

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