Asymmetric dihydroxylation of chiral olefins. High control of diastereofacial selection

Tohru Oishi; Kyo ichiro Iida; Masahiro Hirama

doi:10.1016/S0040-4039(00)73639-2

Asymmetric dihydroxylation of chiral olefins. High control of diastereofacial selection

Tohru Oishi, Kyo ichiro Iida, Masahiro Hirama

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28 Citations (Scopus)

Abstract

Highly diastereoselective dihydroxylation of 4,5-dihydroxy-2-pentenoate with osmium tetroxide using chiral N,N'-dialkyl-2,2′-bipyrrolidine ligands (1) is described. Either syn or anti selection was achieved for acetate (2d) and methyl ether (2e) by employing the enantiomeric ligands.

Original language	English
Pages (from-to)	3573-3576
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	22
DOIs	https://doi.org/10.1016/S0040-4039(00)73639-2
Publication status	Published - May 28 1993
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)73639-2

Cite this

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title = "Asymmetric dihydroxylation of chiral olefins. High control of diastereofacial selection",

abstract = "Highly diastereoselective dihydroxylation of 4,5-dihydroxy-2-pentenoate with osmium tetroxide using chiral N,N'-dialkyl-2,2′-bipyrrolidine ligands (1) is described. Either syn or anti selection was achieved for acetate (2d) and methyl ether (2e) by employing the enantiomeric ligands.",

author = "Tohru Oishi and Iida, {Kyo ichiro} and Masahiro Hirama",

year = "1993",

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journal = "Tetrahedron Letters",

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T1 - Asymmetric dihydroxylation of chiral olefins. High control of diastereofacial selection

AU - Oishi, Tohru

AU - Iida, Kyo ichiro

AU - Hirama, Masahiro

PY - 1993/5/28

Y1 - 1993/5/28

N2 - Highly diastereoselective dihydroxylation of 4,5-dihydroxy-2-pentenoate with osmium tetroxide using chiral N,N'-dialkyl-2,2′-bipyrrolidine ligands (1) is described. Either syn or anti selection was achieved for acetate (2d) and methyl ether (2e) by employing the enantiomeric ligands.

AB - Highly diastereoselective dihydroxylation of 4,5-dihydroxy-2-pentenoate with osmium tetroxide using chiral N,N'-dialkyl-2,2′-bipyrrolidine ligands (1) is described. Either syn or anti selection was achieved for acetate (2d) and methyl ether (2e) by employing the enantiomeric ligands.

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U2 - 10.1016/S0040-4039(00)73639-2

DO - 10.1016/S0040-4039(00)73639-2

M3 - Article

AN - SCOPUS:0027310695

SN - 0040-4039

VL - 34

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EP - 3576

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 22

ER -

Asymmetric dihydroxylation of chiral olefins. High control of diastereofacial selection

Abstract

All Science Journal Classification (ASJC) codes

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