Asymmetric double aldol reaction of chiral acetyloxazolidinone

Hiroshi Furuno; Tadashi Inoue; Atsushi Abiko

doi:10.1016/S0040-4039(02)02021-X

Asymmetric double aldol reaction of chiral acetyloxazolidinone

Hiroshi Furuno, Tadashi Inoue, Atsushi Abiko

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Treatment of chiral oxazolidinone with Bu₂BOTf (2.5 equiv.) and Et₃N (3.0 equiv.) quantitatively produced the doubly borylated enolate, which afforded the double aldol products with high diastereoselectivity after reaction with aldehydes.

Original language	English
Pages (from-to)	8297-8299
Number of pages	3
Journal	Tetrahedron Letters
Volume	43
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(02)02021-X
Publication status	Published - Nov 11 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(02)02021-X

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title = "Asymmetric double aldol reaction of chiral acetyloxazolidinone",

abstract = "Treatment of chiral oxazolidinone with Bu2BOTf (2.5 equiv.) and Et3N (3.0 equiv.) quantitatively produced the doubly borylated enolate, which afforded the double aldol products with high diastereoselectivity after reaction with aldehydes.",

author = "Hiroshi Furuno and Tadashi Inoue and Atsushi Abiko",

note = "Funding Information: This work was supported by a grant from the Ministry of Education, Culture, Sports, Science and Technology of Japan (Grant-in-Aid 10640578 and 13640533).",

year = "2002",

month = nov,

day = "11",

doi = "10.1016/S0040-4039(02)02021-X",

language = "English",

volume = "43",

pages = "8297--8299",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "46",

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T1 - Asymmetric double aldol reaction of chiral acetyloxazolidinone

AU - Furuno, Hiroshi

AU - Inoue, Tadashi

AU - Abiko, Atsushi

N1 - Funding Information: This work was supported by a grant from the Ministry of Education, Culture, Sports, Science and Technology of Japan (Grant-in-Aid 10640578 and 13640533).

PY - 2002/11/11

Y1 - 2002/11/11

N2 - Treatment of chiral oxazolidinone with Bu2BOTf (2.5 equiv.) and Et3N (3.0 equiv.) quantitatively produced the doubly borylated enolate, which afforded the double aldol products with high diastereoselectivity after reaction with aldehydes.

AB - Treatment of chiral oxazolidinone with Bu2BOTf (2.5 equiv.) and Et3N (3.0 equiv.) quantitatively produced the doubly borylated enolate, which afforded the double aldol products with high diastereoselectivity after reaction with aldehydes.

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U2 - 10.1016/S0040-4039(02)02021-X

DO - 10.1016/S0040-4039(02)02021-X

M3 - Article

AN - SCOPUS:0037064482

SN - 0040-4039

VL - 43

SP - 8297

EP - 8299

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

Asymmetric double aldol reaction of chiral acetyloxazolidinone

Abstract

All Science Journal Classification (ASJC) codes

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