Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}

Remarkable Ligand Effect on the Enantioselectivity

T. Hanamoto, Hiroshi Furuno, Y. Sugimoto, J. Inanaga

Research output: Contribution to journal › Article

71 Citations (Scopus)

Abstract

2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93% ee) at room temperature.

Original languageEnglish
Pages (from-to)79-80
Number of pages2
JournalSynlett
Volume1997
Issue number1
Publication statusPublished - Dec 1 1997

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Ytterbium
Enantioselectivity
Phosphates
Ligands
Temperature
2,6-lutidine

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3} : Remarkable Ligand Effect on the Enantioselectivity. / Hanamoto, T.; Furuno, Hiroshi; Sugimoto, Y.; Inanaga, J.

In: Synlett, Vol. 1997, No. 1, 01.12.1997, p. 79-80.

Research output: Contribution to journal › Article

Hanamoto, T, Furuno, H, Sugimoto, Y & Inanaga, J 1997, 'Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}: Remarkable Ligand Effect on the Enantioselectivity', Synlett, vol. 1997, no. 1, pp. 79-80.
Hanamoto T, Furuno H, Sugimoto Y, Inanaga J. Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}: Remarkable Ligand Effect on the Enantioselectivity. Synlett. 1997 Dec 1;1997(1):79-80.
Hanamoto, T. ; Furuno, Hiroshi ; Sugimoto, Y. ; Inanaga, J. / Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3} : Remarkable Ligand Effect on the Enantioselectivity. In: Synlett. 1997 ; Vol. 1997, No. 1. pp. 79-80.
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abstract = "2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93{\%} ee) at room temperature.",
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