Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}

Remarkable Ligand Effect on the Enantioselectivity

T. Hanamoto, Hiroshi Furuno, Y. Sugimoto, J. Inanaga

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93% ee) at room temperature.

Original languageEnglish
Pages (from-to)79-80
Number of pages2
JournalSynlett
Volume1997
Issue number1
Publication statusPublished - Dec 1 1997

Fingerprint

Ytterbium
Enantioselectivity
Phosphates
Ligands
Temperature
2,6-lutidine

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3} : Remarkable Ligand Effect on the Enantioselectivity. / Hanamoto, T.; Furuno, Hiroshi; Sugimoto, Y.; Inanaga, J.

In: Synlett, Vol. 1997, No. 1, 01.12.1997, p. 79-80.

Research output: Contribution to journalArticle

@article{a69ce21816b54a9487e1958f00dd91f1,
title = "Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}: Remarkable Ligand Effect on the Enantioselectivity",
abstract = "2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93{\%} ee) at room temperature.",
author = "T. Hanamoto and Hiroshi Furuno and Y. Sugimoto and J. Inanaga",
year = "1997",
month = "12",
day = "1",
language = "English",
volume = "1997",
pages = "79--80",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "1",

}

TY - JOUR

T1 - Asymmetric Hetero Diels-Alder Reaction Catalyzed by Chiral Ytterbium(III) Phosphate {Yb[(R)-(-)-BNP]3}

T2 - Remarkable Ligand Effect on the Enantioselectivity

AU - Hanamoto, T.

AU - Furuno, Hiroshi

AU - Sugimoto, Y.

AU - Inanaga, J.

PY - 1997/12/1

Y1 - 1997/12/1

N2 - 2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93% ee) at room temperature.

AB - 2,6-Lutidine was found to be an effective additive for the chiral ytterbium(III) phosphate {Yb[(R)-(-)-BNP]3}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93% ee) at room temperature.

UR - http://www.scopus.com/inward/record.url?scp=0002296924&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002296924&partnerID=8YFLogxK

M3 - Article

VL - 1997

SP - 79

EP - 80

JO - Synlett

JF - Synlett

SN - 0936-5214

IS - 1

ER -