Asymmetric hetero Diels-Alder reaction catalyzed by chromium complexes of heterogeneously hybridized salen/salan ligands

Satomi Eno, Hiromichi Egami, Tatsuya Uchida, Tsutomu Katsuki

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Abstract

Various heterogeneously or homogeneously hybridized salen/salan ligands were synthesized, and study of hetero Diels-Alder reactions using their chromium complexes as catalysts revealed that a well-designed heterogeneously hybridized ligand serves as a chiral auxiliary as efficiently as the homogeneously hybridized ligand and its chromium complex has high catalytic activity.

Original languageEnglish
Pages (from-to)632-633
Number of pages2
JournalChemistry Letters
Volume37
Issue number6
DOIs
Publication statusPublished - Jun 5 2008

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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