Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

Masaya Sawamura; Ryoichi Kuwano; Junya Shirai; Yoshihiko Ito

doi:10.1002/chin.199541045

Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

Masaya Sawamura, Ryoichi Kuwano, Junya Shirai, Yoshihiko Ito

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.

Original language	English
Pages (from-to)	347-348
Number of pages	2
Journal	Synlett
Volume	1995
Issue number	4
DOIs	https://doi.org/10.1002/chin.199541045
Publication status	Published - Apr 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1002/chin.199541045

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title = "Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP",

abstract = "Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.",

author = "Masaya Sawamura and Ryoichi Kuwano and Junya Shirai and Yoshihiko Ito",

year = "1995",

month = apr,

doi = "10.1002/chin.199541045",

language = "English",

volume = "1995",

pages = "347--348",

journal = "Synlett",

issn = "0936-5214",

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T1 - Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

AU - Sawamura, Masaya

AU - Kuwano, Ryoichi

AU - Shirai, Junya

AU - Ito, Yoshihiko

PY - 1995/4

Y1 - 1995/4

N2 - Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.

AB - Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.

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DO - 10.1002/chin.199541045

M3 - Article

AN - SCOPUS:0001251142

SN - 0936-5214

VL - 1995

SP - 347

EP - 348

JO - Synlett

JF - Synlett

IS - 4

ER -

Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

Abstract

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