Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

Masaya Sawamura, Ryoichi Kuwano, Junya Shirai, Yoshihiko Ito

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.

Original languageEnglish
Pages (from-to)347-348
Number of pages2
JournalSynlett
Volume1995
Issue number4
DOIs
Publication statusPublished - Apr 1 1995
Externally publishedYes

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phosphine
Hydrosilylation
Rhodium
Chelation
Esters
Alcohols
Ligands
Catalysts

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP. / Sawamura, Masaya; Kuwano, Ryoichi; Shirai, Junya; Ito, Yoshihiko.

In: Synlett, Vol. 1995, No. 4, 01.04.1995, p. 347-348.

Research output: Contribution to journalArticle

Sawamura, Masaya ; Kuwano, Ryoichi ; Shirai, Junya ; Ito, Yoshihiko. / Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP. In: Synlett. 1995 ; Vol. 1995, No. 4. pp. 347-348.
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