Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

Masaya Sawamura, Ryoichi Kuwano, Junya Shirai, Yoshihiko Ito

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Asymmetric hydrosilylation of α-, β-, and γ-keto esters with diphenylsilane in the presence of 1 mol% of a rhodium catalyst containing trans-chelating chiral phosphine ligand EtTRAP gave optically active alcohols with enantiomeric excesses ranging between 32-93%.

Original languageEnglish
Pages (from-to)347-348
Number of pages2
JournalSynlett
Volume1995
Issue number4
DOIs
Publication statusPublished - Apr 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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