Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

Ryoichi Kuwano; Masaya Sawamura; Junya Shirai; Masatoshi Takahashi; Yoshihiko Ito

doi:10.1016/00404-0399(50)0981H-

Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

Ryoichi Kuwano, Masaya Sawamura, Junya Shirai, Masatoshi Takahashi, Yoshihiko Ito

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount ([substrate]/[catalyst] = 100) of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.

Original language	English
Pages (from-to)	5239-5242
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	29
DOIs	https://doi.org/10.1016/00404-0399(50)0981H-
Publication status	Published - Jul 17 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/00404-0399(50)0981H-

Cite this

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title = "Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP",

abstract = "Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount ([substrate]/[catalyst] = 100) of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.",

author = "Ryoichi Kuwano and Masaya Sawamura and Junya Shirai and Masatoshi Takahashi and Yoshihiko Ito",

year = "1995",

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T1 - Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

AU - Kuwano, Ryoichi

AU - Sawamura, Masaya

AU - Shirai, Junya

AU - Takahashi, Masatoshi

AU - Ito, Yoshihiko

PY - 1995/7/17

Y1 - 1995/7/17

N2 - Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount ([substrate]/[catalyst] = 100) of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.

AB - Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount ([substrate]/[catalyst] = 100) of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.

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M3 - Article

AN - SCOPUS:85047671427

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ER -

Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

Abstract

All Science Journal Classification (ASJC) codes

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