Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Yasuro Niidome, Takashi Kawazoe, Sunao Yamada

Research output: Contribution to journalConference article

Abstract

One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

Original languageEnglish
Pages (from-to)119-122
Number of pages4
JournalMolecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
Volume22
Issue number1-4
Publication statusPublished - Dec 1 1999
EventProceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference - Chitose, Jpn
Duration: Oct 12 1998Oct 15 1998

Fingerprint

Maleic Anhydrides
Maleic anhydride
anhydrides
Harmonic generation
Polymer films
harmonic generations
Coloring Agents
Dyes
dyes
Thin films
Water
polymers
water
Vinyl Chloride
carboxyl group
Polymethyl Methacrylate
Polymethyl methacrylates
polymethyl methacrylate
hydrolysis
Hydrolysis

All Science Journal Classification (ASJC) codes

  • Control and Systems Engineering
  • Condensed Matter Physics

Cite this

Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water. / Niidome, Yasuro; Kawazoe, Takashi; Yamada, Sunao.

In: Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics, Vol. 22, No. 1-4, 01.12.1999, p. 119-122.

Research output: Contribution to journalConference article

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