Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Seiji Shinkai, Hideki Nakao, Takaharu Tsuno, Osamu Manabe, Atsuyoshi Ohno

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.

Original languageEnglish
Pages (from-to)849-850
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number13
DOIs
Publication statusPublished - Jan 1 1984
Externally publishedYes

Fingerprint

Flavins
Riboflavin
NAD
Hydrogen
4,6-dinitro-o-cresol
isoalloxazine

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins. / Shinkai, Seiji; Nakao, Hideki; Tsuno, Takaharu; Manabe, Osamu; Ohno, Atsuyoshi.

In: Journal of the Chemical Society, Chemical Communications, No. 13, 01.01.1984, p. 849-850.

Research output: Contribution to journalArticle

Shinkai, Seiji ; Nakao, Hideki ; Tsuno, Takaharu ; Manabe, Osamu ; Ohno, Atsuyoshi. / Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins. In: Journal of the Chemical Society, Chemical Communications. 1984 ; No. 13. pp. 849-850.
@article{664929d232bd4b74bab60d940d2d73ed,
title = "Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins",
abstract = "Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.",
author = "Seiji Shinkai and Hideki Nakao and Takaharu Tsuno and Osamu Manabe and Atsuyoshi Ohno",
year = "1984",
month = "1",
day = "1",
doi = "10.1039/c39840000849",
language = "English",
pages = "849--850",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "13",

}

TY - JOUR

T1 - Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

AU - Shinkai, Seiji

AU - Nakao, Hideki

AU - Tsuno, Takaharu

AU - Manabe, Osamu

AU - Ohno, Atsuyoshi

PY - 1984/1/1

Y1 - 1984/1/1

N2 - Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.

AB - Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.

UR - http://www.scopus.com/inward/record.url?scp=37049103167&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049103167&partnerID=8YFLogxK

U2 - 10.1039/c39840000849

DO - 10.1039/c39840000849

M3 - Article

SP - 849

EP - 850

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 13

ER -