Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Seiji Shinkai; Hideki Nakao; Takaharu Tsuno; Osamu Manabe; Atsuyoshi Ohno

doi:10.1039/c39840000849

Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Seiji Shinkai, Hideki Nakao, Takaharu Tsuno, Osamu Manabe, Atsuyoshi Ohno

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO ₄)₂.

Original language	English
Pages (from-to)	849-850
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/c39840000849
Publication status	Published - Jan 1 1984
Externally published	Yes

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All Science Journal Classification (ASJC) codes

Molecular Medicine

Cite this

Shinkai, S., Nakao, H., Tsuno, T., Manabe, O., & Ohno, A. (1984). Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins. Journal of the Chemical Society, Chemical Communications, (13), 849-850. https://doi.org/10.1039/c39840000849

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AU - Tsuno, Takaharu

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AU - Ohno, Atsuyoshi

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10.1039/c39840000849