Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Seiji Shinkai; Hideki Nakao; Takaharu Tsuno; Osamu Manabe; Atsuyoshi Ohno

doi:10.1039/c39840000849

Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Seiji Shinkai, Hideki Nakao, Takaharu Tsuno, Osamu Manabe, Atsuyoshi Ohno

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO ₄)₂.

Original language	English
Pages (from-to)	849-850
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/c39840000849
Publication status	Published - Jan 1 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins",

abstract = "Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.",

author = "Seiji Shinkai and Hideki Nakao and Takaharu Tsuno and Osamu Manabe and Atsuyoshi Ohno",

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T1 - Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

AU - Shinkai, Seiji

AU - Nakao, Hideki

AU - Tsuno, Takaharu

AU - Manabe, Osamu

AU - Ohno, Atsuyoshi

PY - 1984/1/1

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N2 - Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.

AB - Achiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutan- 2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO 4)2.

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