Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst

Hidekazu Fujita; Tatsuya Uchida; Ryo Irie; Tsutomu Katsuki

doi:10.1246/cl.2007.1092

Asymmetric sulfimidation with cis-β Ru(salalen)CO₂ complexes as catalyst

Hidekazu Fujita, Tatsuya Uchida, Ryo Irie, Tsutomu Katsuki

Division for Experimental Natural Science

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Ru(salalen)(CO)₂ complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) ₂ complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

Original language	English
Pages (from-to)	1092-1093
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	9
DOIs	https://doi.org/10.1246/cl.2007.1092
Publication status	Published - Sept 5 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2007.1092

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abstract = "Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.",

author = "Hidekazu Fujita and Tatsuya Uchida and Ryo Irie and Tsutomu Katsuki",

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AU - Irie, Ryo

AU - Katsuki, Tsutomu

PY - 2007/9/5

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N2 - Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

AB - Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

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Asymmetric sulfimidation with cis-β Ru(salalen)CO₂ complexes as catalyst

Abstract

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