Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst

Hidekazu Fujita, Tatsuya Uchida, Ryo Irie, Tsutomu Katsuki

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

Original languageEnglish
Pages (from-to)1092-1093
Number of pages2
JournalChemistry Letters
Volume36
Issue number9
DOIs
Publication statusPublished - Sep 5 2007

Fingerprint

Carbon Monoxide
Catalysts
Enantioselectivity
X ray diffraction analysis
Irradiation
Ligands

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst. / Fujita, Hidekazu; Uchida, Tatsuya; Irie, Ryo; Katsuki, Tsutomu.

In: Chemistry Letters, Vol. 36, No. 9, 05.09.2007, p. 1092-1093.

Research output: Contribution to journalArticle

Fujita, Hidekazu ; Uchida, Tatsuya ; Irie, Ryo ; Katsuki, Tsutomu. / Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst. In: Chemistry Letters. 2007 ; Vol. 36, No. 9. pp. 1092-1093.
@article{2aa8af4582ba45ff96a54efbfad9d16e,
title = "Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst",
abstract = "Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90{\%} ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.",
author = "Hidekazu Fujita and Tatsuya Uchida and Ryo Irie and Tsutomu Katsuki",
year = "2007",
month = "9",
day = "5",
doi = "10.1246/cl.2007.1092",
language = "English",
volume = "36",
pages = "1092--1093",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "9",

}

TY - JOUR

T1 - Asymmetric sulfimidation with cis-β Ru(salalen)CO2 complexes as catalyst

AU - Fujita, Hidekazu

AU - Uchida, Tatsuya

AU - Irie, Ryo

AU - Katsuki, Tsutomu

PY - 2007/9/5

Y1 - 2007/9/5

N2 - Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

AB - Ru(salalen)(CO)2 complexes were found to serve as catalysts for asymmetric sulfimidation under irradiation, and high enantioselectivity (up to 90% ee) was obtained. In addition, the structures of two Ru(salalen)(CO) 2 complexes that carry the ligands of the same configuration but induce opposite asymmetry to each other, were determined by X-ray diffraction analysis.

UR - http://www.scopus.com/inward/record.url?scp=34948882688&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34948882688&partnerID=8YFLogxK

U2 - 10.1246/cl.2007.1092

DO - 10.1246/cl.2007.1092

M3 - Article

VL - 36

SP - 1092

EP - 1093

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 9

ER -