Asymmetric synthesis of chiral silicon molecules and stereoselective transformations thereof

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Abstract

A variety of functionalized chiral silicon molecules were stereoselectively synthesized from enantio-enriched chiral silanols or chiral silacyclopentenols, which were prepared by highly enantioselective desymmetrization reactions of achiral silicon molecules. The unique reactivity, and substantial bioactivity of the synthesized chiral silicon molecules were disclosed.

Original languageEnglish
Pages (from-to)898-908
Number of pages11
JournalYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume75
Issue number9
DOIs
Publication statusPublished - Jan 1 2017

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Silicon
Molecules
Bioactivity

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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title = "Asymmetric synthesis of chiral silicon molecules and stereoselective transformations thereof",
abstract = "A variety of functionalized chiral silicon molecules were stereoselectively synthesized from enantio-enriched chiral silanols or chiral silacyclopentenols, which were prepared by highly enantioselective desymmetrization reactions of achiral silicon molecules. The unique reactivity, and substantial bioactivity of the synthesized chiral silicon molecules were disclosed.",
author = "Kazunobu Igawa",
year = "2017",
month = "1",
day = "1",
doi = "10.5059/yukigoseikyokaishi.75.898",
language = "English",
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journal = "Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry",
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publisher = "社団法人 有機合成化学協会",
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T1 - Asymmetric synthesis of chiral silicon molecules and stereoselective transformations thereof

AU - Igawa, Kazunobu

PY - 2017/1/1

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N2 - A variety of functionalized chiral silicon molecules were stereoselectively synthesized from enantio-enriched chiral silanols or chiral silacyclopentenols, which were prepared by highly enantioselective desymmetrization reactions of achiral silicon molecules. The unique reactivity, and substantial bioactivity of the synthesized chiral silicon molecules were disclosed.

AB - A variety of functionalized chiral silicon molecules were stereoselectively synthesized from enantio-enriched chiral silanols or chiral silacyclopentenols, which were prepared by highly enantioselective desymmetrization reactions of achiral silicon molecules. The unique reactivity, and substantial bioactivity of the synthesized chiral silicon molecules were disclosed.

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M3 - Review article

VL - 75

SP - 898

EP - 908

JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

SN - 0037-9980

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