Asymmetric total syntheses of xanthatin and 11,13-dihydroxanthatin using a stereocontrolled conjugate allylation to γ-butenolide

Kenji Matsumoto, Kuniyoshi Koyachi, Mitsuru Shindo

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The stereocontrolled conjugate allylation to an optically pure γ-butenolide provided direct and reliable access to a trans-fused series of xanthanolide sesquiterpenoids and allowed for the enantioselective total syntheses of xanthatin and 11,13-dihydroxanthatin to be efficiently achieved.

Original languageEnglish
Pages (from-to)1043-1049
Number of pages7
JournalTetrahedron
Volume69
Issue number3
DOIs
Publication statusPublished - Jan 21 2013

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Allylation
11,13-dihydroxanthatin
butenolide
xanthatin

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Asymmetric total syntheses of xanthatin and 11,13-dihydroxanthatin using a stereocontrolled conjugate allylation to γ-butenolide. / Matsumoto, Kenji; Koyachi, Kuniyoshi; Shindo, Mitsuru.

In: Tetrahedron, Vol. 69, No. 3, 21.01.2013, p. 1043-1049.

Research output: Contribution to journalArticle

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