Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

Kazunobu Igawa; Naoto Kokan; Katsuhiko Tomooka

doi:10.1002/anie.200904922

Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

Kazunobu Igawa, Naoto Kokan, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

Original language	English
Pages (from-to)	728-731
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	4
DOIs	https://doi.org/10.1002/anie.200904922
Publication status	Published - Jan 18 2010

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200904922

Cite this

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abstract = "Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.",

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AU - Kokan, Naoto

AU - Tomooka, Katsuhiko

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Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

Abstract

All Science Journal Classification (ASJC) codes

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