Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

Original languageEnglish
Pages (from-to)728-731
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number4
DOIs
Publication statusPublished - Jan 18 2010

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Esters
Derivatives
Acids
Silicon
Atoms
silanol

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives. / Igawa, Kazunobu; Kokan, Naoto; Tomooka, Katsuhiko.

In: Angewandte Chemie - International Edition, Vol. 49, No. 4, 18.01.2010, p. 728-731.

Research output: Contribution to journalArticle

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