Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

Kazunobu Igawa, Naoto Kokan, Katsuhiko Tomooka

Research output: Contribution to journal › Article

33 Citations (Scopus)

Abstract

Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

Original languageEnglish
Pages (from-to)728-731
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number4
DOIs
Publication statusPublished - Jan 18 2010

Fingerprint

Esters
Derivatives
Acids
Silicon
Atoms
silanol

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives. / Igawa, Kazunobu; Kokan, Naoto; Tomooka, Katsuhiko.

In: Angewandte Chemie - International Edition, Vol. 49, No. 4, 18.01.2010, p. 728-731.

Research output: Contribution to journal › Article

Igawa, K, Kokan, N & Tomooka, K 2010, 'Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives', Angewandte Chemie - International Edition, vol. 49, no. 4, pp. 728-731. https://doi.org/10.1002/anie.200904922
Igawa K, Kokan N, Tomooka K. Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives. Angewandte Chemie - International Edition. 2010 Jan 18;49(4):728-731. https://doi.org/10.1002/anie.200904922
Igawa, Kazunobu ; Kokan, Naoto ; Tomooka, Katsuhiko. / Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 4. pp. 728-731.
@article{319e6e799c2e47f48a4b7005ce65f4d3,
title = "Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives",
abstract = "Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.",
author = "Kazunobu Igawa and Naoto Kokan and Katsuhiko Tomooka",
year = "2010",
month = "1",
day = "18",
doi = "10.1002/anie.200904922",
language = "English",
volume = "49",
pages = "728--731",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "4",

}

TY - JOUR

T1 - Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

AU - Igawa, Kazunobu

AU - Kokan, Naoto

AU - Tomooka, Katsuhiko

PY - 2010/1/18

Y1 - 2010/1/18

N2 - Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

AB - Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

UR - http://www.scopus.com/inward/record.url?scp=74849140411&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=74849140411&partnerID=8YFLogxK

U2 - 10.1002/anie.200904922

DO - 10.1002/anie.200904922

M3 - Article

C2 - 20029860

AN - SCOPUS:74849140411

VL - 49

SP - 728

EP - 731

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 4

ER -

Access to Document