Abstract
Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.
Original language | English |
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Pages (from-to) | 728-731 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 4 |
DOIs | |
Publication status | Published - Jan 18 2010 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)