Asymmetrie synthesis of chiral silacarboxylic acids and their ester derivatives

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Abstract

Sila analogues: The first asymmetric synthesis of silacarboxylic acids with a stereogenic center at the silicon atom has been achieved from chiral nonracemic silanols, without loss of optical purity. Silacarboxylic acids can be converted into their corresponding esters using a Mitsunobu-type reaction.

Original languageEnglish
Pages (from-to)728-731
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number4
DOIs
Publication statusPublished - Jan 18 2010

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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