Atom-transfer radical polymerization by a recycable iron-amine catalyst

Shota Niibayshi, Hideo Nagashima, Kai Hidetomo, Hitoshi Hayakawa, Jin Ren-Hua

Research output: Contribution to conferencePaper

Abstract

A trinuclear iron catalyst shown above is found to be a good catalyst for well-controlled atom-transfer radical polymerization of styrene. The formed polystyrene has a terminal chloride; in fact, post-polymerization with MMA smoothly takes place. The iron species can be removed from the formed polystyrene by precipitation of the polymer from methanol. The iron species can be recovered from the solution quantitatively; 1H NMR spectrum of the recovered iron complex is identical with that of the initial iron compound. The recovered iron catalyst can be used for five repeated experiments of polymerization followed by catalyst recycle.

Original languageEnglish
Number of pages1
Publication statusPublished - Oct 18 2006
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

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Atom transfer radical polymerization
Amines
Iron
Catalysts
Polystyrenes
Polymerization
Iron compounds
Styrene
Methanol
Nuclear magnetic resonance
Polymers
Experiments

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Niibayshi, S., Nagashima, H., Hidetomo, K., Hayakawa, H., & Ren-Hua, J. (2006). Atom-transfer radical polymerization by a recycable iron-amine catalyst. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.

Atom-transfer radical polymerization by a recycable iron-amine catalyst. / Niibayshi, Shota; Nagashima, Hideo; Hidetomo, Kai; Hayakawa, Hitoshi; Ren-Hua, Jin.

2006. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.

Research output: Contribution to conferencePaper

Niibayshi, S, Nagashima, H, Hidetomo, K, Hayakawa, H & Ren-Hua, J 2006, 'Atom-transfer radical polymerization by a recycable iron-amine catalyst' Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan, 5/24/06 - 5/26/06, .
Niibayshi S, Nagashima H, Hidetomo K, Hayakawa H, Ren-Hua J. Atom-transfer radical polymerization by a recycable iron-amine catalyst. 2006. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.
Niibayshi, Shota ; Nagashima, Hideo ; Hidetomo, Kai ; Hayakawa, Hitoshi ; Ren-Hua, Jin. / Atom-transfer radical polymerization by a recycable iron-amine catalyst. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.1 p.
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