Atom transfer radical polymerization by solvent-stabilized (Me3TACN)FeX2: A practical access to reusable iron(II) catalysts

So Ichiro Nakanishi; Mitsunobu Kawamura; Yusuke Sunada; Hideo Nagashima

doi:10.1039/c5py01762a

Atom transfer radical polymerization by solvent-stabilized (Me₃TACN)FeX₂: A practical access to reusable iron(II) catalysts

So Ichiro Nakanishi, Mitsunobu Kawamura, Yusuke Sunada, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new Fe(ii) complex (Me₃TACN)FeBr₂(κ-NCMe), which is stabilized by a weakly coordinating solvent, was prepared as an efficient and reusable catalyst for atom transfer radical polymerization (ATRP) of styrene, MMA, and BA. The complex was conveniently generated from either [(Me₃TACN)Fe(μ-Br)₃(Me₃TACN)]⁺[Br]^- or a mixture of FeBr₂ and Me₃TACN in MeCN.

Original language	English
Pages (from-to)	1037-1048
Number of pages	12
Journal	Polymer Chemistry
Volume	7
Issue number	5
DOIs	https://doi.org/10.1039/c5py01762a
Publication status	Published - Feb 7 2016

All Science Journal Classification (ASJC) codes

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

Access to Document

10.1039/c5py01762a

Cite this

@article{44a3683f941a4674be62a2f17924409a,

title = "Atom transfer radical polymerization by solvent-stabilized (Me3TACN)FeX2: A practical access to reusable iron(II) catalysts",

abstract = "A new Fe(ii) complex (Me3TACN)FeBr2(κ-NCMe), which is stabilized by a weakly coordinating solvent, was prepared as an efficient and reusable catalyst for atom transfer radical polymerization (ATRP) of styrene, MMA, and BA. The complex was conveniently generated from either [(Me3TACN)Fe(μ-Br)3(Me3TACN)]+[Br]- or a mixture of FeBr2 and Me3TACN in MeCN.",

author = "Nakanishi, {So Ichiro} and Mitsunobu Kawamura and Yusuke Sunada and Hideo Nagashima",

year = "2016",

month = feb,

day = "7",

doi = "10.1039/c5py01762a",

language = "English",

volume = "7",

pages = "1037--1048",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Atom transfer radical polymerization by solvent-stabilized (Me3TACN)FeX2

T2 - A practical access to reusable iron(II) catalysts

AU - Nakanishi, So Ichiro

AU - Kawamura, Mitsunobu

AU - Sunada, Yusuke

AU - Nagashima, Hideo

PY - 2016/2/7

Y1 - 2016/2/7

N2 - A new Fe(ii) complex (Me3TACN)FeBr2(κ-NCMe), which is stabilized by a weakly coordinating solvent, was prepared as an efficient and reusable catalyst for atom transfer radical polymerization (ATRP) of styrene, MMA, and BA. The complex was conveniently generated from either [(Me3TACN)Fe(μ-Br)3(Me3TACN)]+[Br]- or a mixture of FeBr2 and Me3TACN in MeCN.

AB - A new Fe(ii) complex (Me3TACN)FeBr2(κ-NCMe), which is stabilized by a weakly coordinating solvent, was prepared as an efficient and reusable catalyst for atom transfer radical polymerization (ATRP) of styrene, MMA, and BA. The complex was conveniently generated from either [(Me3TACN)Fe(μ-Br)3(Me3TACN)]+[Br]- or a mixture of FeBr2 and Me3TACN in MeCN.

UR - http://www.scopus.com/inward/record.url?scp=84955597447&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84955597447&partnerID=8YFLogxK

U2 - 10.1039/c5py01762a

DO - 10.1039/c5py01762a

M3 - Article

AN - SCOPUS:84955597447

SN - 1759-9954

VL - 7

SP - 1037

EP - 1048

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 5

ER -

Atom transfer radical polymerization by solvent-stabilized (Me₃TACN)FeX₂: A practical access to reusable iron(II) catalysts

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this