Atomic-resolution analysis of degradation phenomena in SOFCS: A case study of SO2 poisoning in LSM cathodes

Takeshi Daio, Pratoy Mitra, Stephen M. Lyth, Kazunari Sasaki

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Solid oxide fuel cell (SOFC) degradation studies are often performed by scanning transmission electron microscopy (STEM), scanning electron microscopy (SEM), and X-ray diffraction (XRD). However, it is difficult to use these techniques to observe processes occurring at the smallest scales. Here, we study sulfur poisoning of La0.8Sr0.2MnO3−δ (LSM) cathodes as a model case for atomic resolution scanning transmission electron microscopy (STEM) analysis with energy dispersive X-ray diffraction (EDX). Significant SrSO4 nanoparticle formation is observed after SO2 exposure, especially at grain boundaries in the LSM. In addition, La2O3 formation inside the grain was also confirmed. The formation of SrSO4 is identified with irreversible SOFC degradation, in addition to simple SO2 adsorption, which is reversible.

Original languageEnglish
Pages (from-to)12214-12221
Number of pages8
JournalInternational Journal of Hydrogen Energy
Volume41
Issue number28
DOIs
Publication statusPublished - Jul 27 2016

Fingerprint

poisoning
Cathodes
cathodes
solid oxide fuel cells
degradation
Solid oxide fuel cells (SOFC)
Degradation
Scanning electron microscopy
scanning electron microscopy
Transmission electron microscopy
X ray diffraction
transmission electron microscopy
diffraction
Grain boundaries
x rays
sulfur
Sulfur
grain boundaries
Nanoparticles
Adsorption

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Atomic-resolution analysis of degradation phenomena in SOFCS : A case study of SO2 poisoning in LSM cathodes. / Daio, Takeshi; Mitra, Pratoy; Lyth, Stephen M.; Sasaki, Kazunari.

In: International Journal of Hydrogen Energy, Vol. 41, No. 28, 27.07.2016, p. 12214-12221.

Research output: Contribution to journalArticle

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