Autoaccelerative diazo coupling with calix[4]arene: Unusual co-operativity of the calixarene hydroxy groups

Seiji Shinkai, Koji Araki, Jiro Shibata, Osamu Manabe

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Diazo coupling between calix[4]arene and p-nitrobenzenediazonium ion selectively afforded the tetrasubstituted calix[4]arene and almost no mono-, di-, and tri-substituted calix[4]arenes even in the presence of unchanged calix[4]arene: the unusual all-or-nothing substitution is attributed to the specific hydrogen-bonding effect among the calixarene OH groups.

Original languageEnglish
Pages (from-to)195-196
Number of pages2
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number1
DOIs
Publication statusPublished - Jan 1 1989
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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