Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

Original languageEnglish
Pages (from-to)4856-4861
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number30
DOIs
Publication statusPublished - 2016

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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