Azaferrocene-Based PNP-Type Pincer Ligand

Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

Original languageEnglish
Pages (from-to)4856-4861
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number30
DOIs
Publication statusPublished - Jan 1 2016

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Nitrogen fixation
Molybdenum
Chromium
Iron
Ligands
Bearings (structural)
Coordination Complexes
X ray analysis
Transition metals

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Azaferrocene-Based PNP-Type Pincer Ligand : Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation. / Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari; Tanaka, Hiromasa; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 30, 01.01.2016, p. 4856-4861.

Research output: Contribution to journalArticle

Kuriyama, Shogo ; Arashiba, Kazuya ; Nakajima, Kazunari ; Tanaka, Hiromasa ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Azaferrocene-Based PNP-Type Pincer Ligand : Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 30. pp. 4856-4861.
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