Benzimidazobenzothiazole-Based Bipolar Hosts to Harvest Nearly All of the Excitons from Blue Delayed Fluorescence and Phosphorescent Organic Light-Emitting Diodes

Lin Song Cui, Jong Uk Kim, Hiroko Nomura, Hajime Nakanotani, Chihaya Adachi

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59 Citations (Scopus)

Abstract

Much effort has been devoted to developing highly efficient organic light-emitting diodes (OLEDs) that function through phosphorescence or thermally activated delayed fluorescence (TADF). However, efficient host materials for blue TADF and phosphorescent guest emitters are limited because of their requirement of high triplet energy levels. Herein, we report the rigid acceptor unit benzimidazobenzothiazole (BID-BT), which is suitable for use in bipolar hosts in blue OLEDs. The designed host materials, based on BID-BT, possess high triplet energy and bipolar carrier transport ability. Both blue TADF and phosphorescent OLEDs containing BID-BT-based derivatives exhibit external quantum efficiencies as high as 20 %, indicating that these hosts allow efficient triplet exciton confinement appropriate for blue TADF and phosphorescent guest emitters. Gotta catch them all: Over 20 % external quantum efficiencies were achieved in both blue thermally activated delayed fluorescence (TADF) and phosphorescent organic light-emitting diodes (OLEDs) using benzimidazobenzothiazole bipolar host materials.

Original languageEnglish
Pages (from-to)6864-6868
Number of pages5
JournalAngewandte Chemie - International Edition
Volume55
Issue number24
DOIs
Publication statusPublished - Jan 1 2016

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Organic light emitting diodes (OLED)
Excitons
Fluorescence
Quantum efficiency
Phosphorescence
Carrier transport
Electron energy levels
LDS 751
Derivatives

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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title = "Benzimidazobenzothiazole-Based Bipolar Hosts to Harvest Nearly All of the Excitons from Blue Delayed Fluorescence and Phosphorescent Organic Light-Emitting Diodes",
abstract = "Much effort has been devoted to developing highly efficient organic light-emitting diodes (OLEDs) that function through phosphorescence or thermally activated delayed fluorescence (TADF). However, efficient host materials for blue TADF and phosphorescent guest emitters are limited because of their requirement of high triplet energy levels. Herein, we report the rigid acceptor unit benzimidazobenzothiazole (BID-BT), which is suitable for use in bipolar hosts in blue OLEDs. The designed host materials, based on BID-BT, possess high triplet energy and bipolar carrier transport ability. Both blue TADF and phosphorescent OLEDs containing BID-BT-based derivatives exhibit external quantum efficiencies as high as 20 {\%}, indicating that these hosts allow efficient triplet exciton confinement appropriate for blue TADF and phosphorescent guest emitters. Gotta catch them all: Over 20 {\%} external quantum efficiencies were achieved in both blue thermally activated delayed fluorescence (TADF) and phosphorescent organic light-emitting diodes (OLEDs) using benzimidazobenzothiazole bipolar host materials.",
author = "Cui, {Lin Song} and Kim, {Jong Uk} and Hiroko Nomura and Hajime Nakanotani and Chihaya Adachi",
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AU - Cui, Lin Song

AU - Kim, Jong Uk

AU - Nomura, Hiroko

AU - Nakanotani, Hajime

AU - Adachi, Chihaya

PY - 2016/1/1

Y1 - 2016/1/1

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AB - Much effort has been devoted to developing highly efficient organic light-emitting diodes (OLEDs) that function through phosphorescence or thermally activated delayed fluorescence (TADF). However, efficient host materials for blue TADF and phosphorescent guest emitters are limited because of their requirement of high triplet energy levels. Herein, we report the rigid acceptor unit benzimidazobenzothiazole (BID-BT), which is suitable for use in bipolar hosts in blue OLEDs. The designed host materials, based on BID-BT, possess high triplet energy and bipolar carrier transport ability. Both blue TADF and phosphorescent OLEDs containing BID-BT-based derivatives exhibit external quantum efficiencies as high as 20 %, indicating that these hosts allow efficient triplet exciton confinement appropriate for blue TADF and phosphorescent guest emitters. Gotta catch them all: Over 20 % external quantum efficiencies were achieved in both blue thermally activated delayed fluorescence (TADF) and phosphorescent organic light-emitting diodes (OLEDs) using benzimidazobenzothiazole bipolar host materials.

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