Bioactive titania gel layers formed by chemical treatment of Ti substrate with a H2O2/HCl solution

Xiao Xiang Wang, Satoshi Hayakawa, Kanji Tsuru, Akiyoshi Osaka

Research output: Contribution to journalArticle

218 Citations (Scopus)

Abstract

An amorphous titania gel layer was formed on the titanium surface after the titanium specimen was treated with a H2O2/0.1m HCl solution at 80°C. The thickness of the gel layer increased almost linearly with the period of the treatment. A subsequent heat treatment above 300°C transformed gradually the amorphous gel to the anatase crystal structure and the rutile started to appear after heat treatment at 600°C. Meanwhile, the densification of the gel occurred significantly after heat treatment above 700°C. Similar to the sol-gel derived titania gel coatings, titania gel layers obtained in the present study exhibited in vitro apatite deposition ability after the gel layers exceeded a minimum thickness (0.2 μm) and was subsequently heated in a proper temperature range (400-600°C).

Original languageEnglish
Pages (from-to)1353-1357
Number of pages5
JournalBiomaterials
Volume23
Issue number5
DOIs
Publication statusPublished - Mar 1 2002

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Gels
Titanium
Substrates
Heat treatment
Hot Temperature
Apatites
Apatite
titanium dioxide
Densification
Titanium dioxide
Polymethyl Methacrylate
Sol-gels
Crystal structure
Coatings
Temperature

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Ceramics and Composites
  • Biophysics
  • Biomaterials
  • Mechanics of Materials

Cite this

Bioactive titania gel layers formed by chemical treatment of Ti substrate with a H2O2/HCl solution. / Wang, Xiao Xiang; Hayakawa, Satoshi; Tsuru, Kanji; Osaka, Akiyoshi.

In: Biomaterials, Vol. 23, No. 5, 01.03.2002, p. 1353-1357.

Research output: Contribution to journalArticle

Wang, Xiao Xiang ; Hayakawa, Satoshi ; Tsuru, Kanji ; Osaka, Akiyoshi. / Bioactive titania gel layers formed by chemical treatment of Ti substrate with a H2O2/HCl solution. In: Biomaterials. 2002 ; Vol. 23, No. 5. pp. 1353-1357.
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