TY - JOUR
T1 - Bioinorganic approach to the type-I and type-II copper proteins. Synthesis and properties of copper(II) complexes with tripod-like ligands containing three or four door species
AU - Takahashi, Kazuhiro
AU - Ogawa, Eiji
AU - Oishi, Naoyasu
AU - Nishida, Yuzo
AU - Kida, Sigeo
PY - 1982
Y1 - 1982
N2 - Copper(II) complexes with new tripod-like quadridentate ligands containing three or four donor species, such as benzimidazole, thioether and phenol, were prepared. The ESR and electronic spectral studies have revealed that these complexes are classified into three types, that is, four-coordinated, five-coordinated trigonal bipyramindal and five-coordinated tetragonal pyramidal complexes, and that some of them are good models for blue(Type-I) and non-blue(Type-II) copper proteins.
AB - Copper(II) complexes with new tripod-like quadridentate ligands containing three or four donor species, such as benzimidazole, thioether and phenol, were prepared. The ESR and electronic spectral studies have revealed that these complexes are classified into three types, that is, four-coordinated, five-coordinated trigonal bipyramindal and five-coordinated tetragonal pyramidal complexes, and that some of them are good models for blue(Type-I) and non-blue(Type-II) copper proteins.
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U2 - 10.1016/S0020-1693(00)85796-5
DO - 10.1016/S0020-1693(00)85796-5
M3 - Article
AN - SCOPUS:0002036302
SN - 0020-1693
VL - 66
SP - 97
EP - 103
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - C
ER -