Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate

Miho Hashioka, Ken Sakai, Taro Tsubomura

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate, [Pd2Cl2(C25H46P2) 2].2C2H3N, has been prepared, and the crystal structure determined. The two approximately square-planar ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factors between the diphosphine ligands.

Original languageEnglish
Pages (from-to)1244-1247
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number9
DOIs
Publication statusPublished - Sep 15 1998
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

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