Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand

Kazuhisa Yamasumi, Keiichi Nishimura, Yutaka Hisamune, Yusuke Nagae, Tomoki Uchiyama, Kazutaka Kamitani, Tomoyasu Hirai, Maiko Nishibori, Shigeki Mori, Satoru Karasawa, Tatsuhisa Kato, Ko Furukawa, Masatoshi Ishida, Hiroyuki Furuta

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A contracted doubly N-confused dioxohexaphyrin(1.1.1.1.1.0) complex consisting of two paramagnetic copper metals and open-shell π-radical ligand was synthesized as a new multi-heterospin motif. X-ray spectroscopy supported the divalent character of the inner copper centers, and electron paramagnetic resonance and magnetometric studies suggested the presence of unpaired d electrons strongly antiferromagnetically coupled with π-radicals delocalized on the macrocycle. The 25 π non-innocent dioxohexaphyrin ligand allowed the facile interconversion between antiaromatic 24 π and aromatic 26 π species, respectively, upon redox reactions.

Original languageEnglish
Pages (from-to)15322-15326
Number of pages5
JournalChemistry - A European Journal
Volume23
Issue number61
DOIs
Publication statusPublished - Nov 2 2017

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Copper
Ligands
Redox reactions
X ray spectroscopy
Paramagnetic resonance
Metals
Electrons

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand. / Yamasumi, Kazuhisa; Nishimura, Keiichi; Hisamune, Yutaka; Nagae, Yusuke; Uchiyama, Tomoki; Kamitani, Kazutaka; Hirai, Tomoyasu; Nishibori, Maiko; Mori, Shigeki; Karasawa, Satoru; Kato, Tatsuhisa; Furukawa, Ko; Ishida, Masatoshi; Furuta, Hiroyuki.

In: Chemistry - A European Journal, Vol. 23, No. 61, 02.11.2017, p. 15322-15326.

Research output: Contribution to journalArticle

Yamasumi, K, Nishimura, K, Hisamune, Y, Nagae, Y, Uchiyama, T, Kamitani, K, Hirai, T, Nishibori, M, Mori, S, Karasawa, S, Kato, T, Furukawa, K, Ishida, M & Furuta, H 2017, 'Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand', Chemistry - A European Journal, vol. 23, no. 61, pp. 15322-15326. https://doi.org/10.1002/chem.201704321
Yamasumi, Kazuhisa ; Nishimura, Keiichi ; Hisamune, Yutaka ; Nagae, Yusuke ; Uchiyama, Tomoki ; Kamitani, Kazutaka ; Hirai, Tomoyasu ; Nishibori, Maiko ; Mori, Shigeki ; Karasawa, Satoru ; Kato, Tatsuhisa ; Furukawa, Ko ; Ishida, Masatoshi ; Furuta, Hiroyuki. / Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 61. pp. 15322-15326.
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