Bis(1,3-dithiol-2-ylidene)-Substituted Subtriazachlorin

A Subphthalocyanine Analogue with Redox Properties

Yemei Wang, Shigeki Mori, Hiroyuki Furuta, Soji Shimizu

Research output: Contribution to journalArticle

Abstract

Bis(1,3-dithiol-2-ylidene)-substituted subtriazachlorin was formed because of an unusual reaction of a 1,3-dithiole-2-one-fused subphthalocyanine in a triethylphosphite-mediated tetrathiafulvalene synthesis. In this novel molecule, the bis(1,3-dithiol-2-ylidene)ethane moiety and subtriazachlorin structure are fused, resulting in an electron-donating ability and broad absorption in the near-infrared region.

Original languageEnglish
Pages (from-to)10975-10979
Number of pages5
JournalAngewandte Chemie - International Edition
Volume58
Issue number32
DOIs
Publication statusPublished - Aug 5 2019

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Ethane
Infrared radiation
Molecules
Electrons
Oxidation-Reduction
dithiol
tetrathiafulvalene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Bis(1,3-dithiol-2-ylidene)-Substituted Subtriazachlorin : A Subphthalocyanine Analogue with Redox Properties. / Wang, Yemei; Mori, Shigeki; Furuta, Hiroyuki; Shimizu, Soji.

In: Angewandte Chemie - International Edition, Vol. 58, No. 32, 05.08.2019, p. 10975-10979.

Research output: Contribution to journalArticle

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