Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate

Ken Sakai, Mina Mizota, Norinobu Akiyama

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the title compound, [Pt(C10H8N2)(C 5H6N2)2][Pt(CN)4] ·-2H2O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π-π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt⋯Pt distances [5.2034 (6) and 4.5599 (6) Å] alternate along the one-dimensional stack.

Original languageEnglish
Pages (from-to)m88-m90
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number1
DOIs
Publication statusPublished - Jan 1 2004

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Platinum
Anions
platinum
Negative ions
Positive ions
anions
cations
Divalent Cations
Coulomb interactions
Static Electricity
Cations
Stabilization
Salts
stabilization
electrostatics
salts
Crystals
crystals
interactions
alpha-aminopyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate. / Sakai, Ken; Mizota, Mina; Akiyama, Norinobu.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 1, 01.01.2004, p. m88-m90.

Research output: Contribution to journalArticle

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