Bis(2,2′-bipyridine-κ 2N,N′)(1,10-phen-anthroline-κ 2N,N′)ruthenium(II) tetra-cyanoplatinate(II)

Ken Sakai; Yoshinobu Miyabe

doi:10.1107/S0108270103029500

Bis(2,2′-bipyridine-κ ²N,N′)(1,10-phen-anthroline-κ ²N,N′)ruthenium(II) tetra-cyanoplatinate(II)

Ken Sakai, Yoshinobu Miyabe

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title compound, [Ru(C₁₀H₈N₂) ₂(C₁₂H₈N₂)][Pt(CN)₄], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)₄]^2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

Original language	English
Pages (from-to)	m69-m72
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S0108270103029500
Publication status	Published - Feb 1 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry, Genetics and Molecular Biology(all)

Access to Document

10.1107/S0108270103029500

Cite this

@article{1be9f38c079a4d6e8ebd177b3885b579,

title = "Bis(2,2′-bipyridine-κ 2N,N′)(1,10-phen-anthroline-κ 2N,N′)ruthenium(II) tetra-cyanoplatinate(II)",

abstract = "In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) {\AA}.",

author = "Ken Sakai and Yoshinobu Miyabe",

year = "2004",

month = feb,

day = "1",

doi = "10.1107/S0108270103029500",

language = "English",

volume = "60",

pages = "m69--m72",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - Bis(2,2′-bipyridine-κ 2N,N′)(1,10-phen-anthroline-κ 2N,N′)ruthenium(II) tetra-cyanoplatinate(II)

AU - Sakai, Ken

AU - Miyabe, Yoshinobu

PY - 2004/2/1

Y1 - 2004/2/1

N2 - In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

AB - In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

UR - http://www.scopus.com/inward/record.url?scp=1642318029&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1642318029&partnerID=8YFLogxK

U2 - 10.1107/S0108270103029500

DO - 10.1107/S0108270103029500

M3 - Article

C2 - 14767117

AN - SCOPUS:1642318029

SN - 0108-2701

VL - 60

SP - m69-m72

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Bis(2,2′-bipyridine-κ ²N,N′)(1,10-phen-anthroline-κ ²N,N′)ruthenium(II) tetra-cyanoplatinate(II)

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this