TY - JOUR
T1 - Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphen-yl)carbamo- yl]-2,2′-bi-pyridine-4-carboxyl-ate}ruthenium(II) bis-[hexa-fluorido- phosphate(V)]
AU - Hirahara, Masanari
AU - Masaoka, Shigeyuki
AU - Sakai, Ken
PY - 2009
Y1 - 2009
N2 - In the title compound, [Ru(C10H8N2)2(C21H18N4O4)](PF6)2, the Ru II complex cation reveals a slightly distorted octa-hedral coordination. The coordination bonds of the 4,4′-substituted bipyridyl donors [Ru - N = 2.038 (3) and 2.051 (3) Å] are shorter than those of the 2,2′-bipyridyl donors [Ru - N1 = 2.065 (3)-2.077 (3) Å], due to the electron-withdrawing effects of the substituents at the 4,4′-positions. The angles between the pyridyl planes of the three bipyridyl ligands are 1.5 (2), 6.3 (3) and 8.7 (2)°, respectively. The cations are connected by anions via N - H⋯F inter-actions.
AB - In the title compound, [Ru(C10H8N2)2(C21H18N4O4)](PF6)2, the Ru II complex cation reveals a slightly distorted octa-hedral coordination. The coordination bonds of the 4,4′-substituted bipyridyl donors [Ru - N = 2.038 (3) and 2.051 (3) Å] are shorter than those of the 2,2′-bipyridyl donors [Ru - N1 = 2.065 (3)-2.077 (3) Å], due to the electron-withdrawing effects of the substituents at the 4,4′-positions. The angles between the pyridyl planes of the three bipyridyl ligands are 1.5 (2), 6.3 (3) and 8.7 (2)°, respectively. The cations are connected by anions via N - H⋯F inter-actions.
UR - http://www.scopus.com/inward/record.url?scp=60349127602&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=60349127602&partnerID=8YFLogxK
U2 - 10.1107/S1600536809002360
DO - 10.1107/S1600536809002360
M3 - Article
C2 - 21581819
AN - SCOPUS:60349127602
SN - 1600-5368
VL - 65
SP - m228-m229
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -