Bis[(2,3,6,7,12,13,16,17-octaethylporphycenato)oxomolybdenum(V)] hexamolybdate(VI)

Daisuke Maeda, Isao Aritome, Hisashi Shimakoshi, Yoshio Hisaeda

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, [Mo(C36H44N4)O] 2[Mo6O19], contains a five-coordinate molybdenum-porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter-anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582(9) and 3.031(9), respectively.

Original languageEnglish
Pages (from-to)m1272-m1274
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number6
DOIs
Publication statusPublished - Jun 1 2006

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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