TY - JOUR
T1 - Bis[(2,3,6,7,12,13,16,17-octaethylporphycenato)oxomolybdenum(V)] hexamolybdate(VI)
AU - Maeda, Daisuke
AU - Aritome, Isao
AU - Shimakoshi, Hisashi
AU - Hisaeda, Yoshio
PY - 2006/6/1
Y1 - 2006/6/1
N2 - The title compound, [Mo(C36H44N4)O] 2[Mo6O19], contains a five-coordinate molybdenum-porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter-anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582(9) and 3.031(9), respectively.
AB - The title compound, [Mo(C36H44N4)O] 2[Mo6O19], contains a five-coordinate molybdenum-porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter-anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582(9) and 3.031(9), respectively.
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U2 - 10.1107/S1600536806016461
DO - 10.1107/S1600536806016461
M3 - Article
AN - SCOPUS:33744997398
SN - 1600-5368
VL - 62
SP - m1272-m1274
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 6
ER -