Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate

Ken Sakai, Eri Ishigami

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The title compound, [Pt2(μ-C4O2) 2(NH3)4]2(ClO4) 4, involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt4 II cation, in which the interdimer association is stabilized by four hydrogen bonds formed between the ammines and the butyrate O atoms. The intradimer and interdimer Pt-Pt distances within these tetraplatinum(II) chain cations are, respectively, 2.9881 (4) and 3.2619 (6) Å for one set of dimers, and 3.0246 (4) and 3.3049 (6) Å for the other set of dimers.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number1
DOIs
Publication statusPublished - Jan 1 2004
Externally publishedYes

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Platinum
Dimers
Cisplatin
Cations
platinum
Positive ions
dimers
ammines
cations
Butyrates
Hydrogen
Hydrogen bonds
Association reactions
inversions
hydrogen bonds
Atoms
atoms
perchlorate

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate. / Sakai, Ken; Ishigami, Eri.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 1, 01.01.2004.

Research output: Contribution to journalArticle

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