Bis(guanidinium) bis(oxalato)platinate(II)

Ken Sakai, Norinobu Akiyama, Mina Mizota, Kazuo Yokokawa, Yoshimi Yokoyama

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound, (CH6N3)2[Pt(C 2O4)2] or (guanidinium)2[Pt(ox) 2] (ox = oxalate), possesses an intriguing three-dimensional hydrogen-bonding network in the crystal structure, where extensive hydrogen bonds are formed between N - H(guanidinium) units and O atoms of oxalates [N⋯ = 2.913 (5)-3.197 (5) Å]. The [Pt(ox)2]2- anions stack weakly in a one-dimensional manner, with an intermolecular Pt⋯Pt distance of 3.5876 (7) Å. The Pt atom is located at an inversion centre.

Original languageEnglish
Pages (from-to)m408-m410
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

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Oxalates
Guanidine
oxalates
Hydrogen bonds
Atoms
Anions
atoms
Negative ions
Crystal structure
inversions
hydrogen bonds
anions
crystal structure
hydrogen

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Bis(guanidinium) bis(oxalato)platinate(II). / Sakai, Ken; Akiyama, Norinobu; Mizota, Mina; Yokokawa, Kazuo; Yokoyama, Yoshimi.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 7, 01.07.2003, p. m408-m410.

Research output: Contribution to journalArticle

Sakai, Ken ; Akiyama, Norinobu ; Mizota, Mina ; Yokokawa, Kazuo ; Yokoyama, Yoshimi. / Bis(guanidinium) bis(oxalato)platinate(II). In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 7. pp. m408-m410.
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