Bis(guanidinium) bis(oxalato)platinate(II)

Ken Sakai; Norinobu Akiyama; Mina Mizota; Kazuo Yokokawa; Yoshimi Yokoyama

doi:10.1107/S1600536803011802

Bis(guanidinium) bis(oxalato)platinate(II)

Ken Sakai, Norinobu Akiyama, Mina Mizota, Kazuo Yokokawa, Yoshimi Yokoyama

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The title compound, (CH₆N₃)₂[Pt(C ₂O₄)₂] or (guanidinium)₂[Pt(ox) ₂] (ox = oxalate), possesses an intriguing three-dimensional hydrogen-bonding network in the crystal structure, where extensive hydrogen bonds are formed between N - H(guanidinium) units and O atoms of oxalates [N⋯ = 2.913 (5)-3.197 (5) Å]. The [Pt(ox)₂]^2- anions stack weakly in a one-dimensional manner, with an intermolecular Pt⋯Pt distance of 3.5876 (7) Å. The Pt atom is located at an inversion centre.

Original language	English
Pages (from-to)	m408-m410
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803011802
Publication status	Published - Jul 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Bis(guanidinium) bis(oxalato)platinate(II)",

abstract = "The title compound, (CH6N3)2[Pt(C 2O4)2] or (guanidinium)2[Pt(ox) 2] (ox = oxalate), possesses an intriguing three-dimensional hydrogen-bonding network in the crystal structure, where extensive hydrogen bonds are formed between N - H(guanidinium) units and O atoms of oxalates [N⋯ = 2.913 (5)-3.197 (5) {\AA}]. The [Pt(ox)2]2- anions stack weakly in a one-dimensional manner, with an intermolecular Pt⋯Pt distance of 3.5876 (7) {\AA}. The Pt atom is located at an inversion centre.",

author = "Ken Sakai and Norinobu Akiyama and Mina Mizota and Kazuo Yokokawa and Yoshimi Yokoyama",

year = "2003",

month = jul,

doi = "10.1107/S1600536803011802",

language = "English",

volume = "59",

pages = "m408--m410",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Bis(guanidinium) bis(oxalato)platinate(II)

AU - Sakai, Ken

AU - Akiyama, Norinobu

AU - Mizota, Mina

AU - Yokokawa, Kazuo

AU - Yokoyama, Yoshimi

PY - 2003/7

Y1 - 2003/7

N2 - The title compound, (CH6N3)2[Pt(C 2O4)2] or (guanidinium)2[Pt(ox) 2] (ox = oxalate), possesses an intriguing three-dimensional hydrogen-bonding network in the crystal structure, where extensive hydrogen bonds are formed between N - H(guanidinium) units and O atoms of oxalates [N⋯ = 2.913 (5)-3.197 (5) Å]. The [Pt(ox)2]2- anions stack weakly in a one-dimensional manner, with an intermolecular Pt⋯Pt distance of 3.5876 (7) Å. The Pt atom is located at an inversion centre.

AB - The title compound, (CH6N3)2[Pt(C 2O4)2] or (guanidinium)2[Pt(ox) 2] (ox = oxalate), possesses an intriguing three-dimensional hydrogen-bonding network in the crystal structure, where extensive hydrogen bonds are formed between N - H(guanidinium) units and O atoms of oxalates [N⋯ = 2.913 (5)-3.197 (5) Å]. The [Pt(ox)2]2- anions stack weakly in a one-dimensional manner, with an intermolecular Pt⋯Pt distance of 3.5876 (7) Å. The Pt atom is located at an inversion centre.

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JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Bis(guanidinium) bis(oxalato)platinate(II)

Abstract

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