Bismuth-induced integration of solar energy conversion with synergistic low-temperature catalysis in Ce1-xBixO2-δ nanorods

Dong Jiang, Wenzhong Wang, Erping Gao, Ling Zhang, Songmei Sun

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

For conventional photocatalysis, the energy threshold rather than merely the spectral response is always restricted that the infrared part (48% of solar energy) has never been efficiently utilized, undesirably elevating the temperature and damaging the photon-to-electron conversion. It remains challenging to conquer the IR-related contradiction and integrate the infrared energy into the solar energy conversion. Herein, we logically designed a Bi-induced synergistic photo/thermocatalyst (fluorite Ce1-xBi xO2-δ nanorods), where the coupled ionic conductivity accompanying highly reductive Bi and concomitant oxygen vacancies helped bring about integration of photocatalysis with synergistic low temperature (20-80 C, IR-driven) catalysis, promising for the effective utilization of infrared energy. More generally, through our results a feasible methodology is verified in detail that integration of semiconductor photocatalysis with solid state ionics may help design brand new catalysts, shedding light on the practical solar energy conversion.

Original languageEnglish
Pages (from-to)24242-24249
Number of pages8
JournalJournal of Physical Chemistry C
Volume117
Issue number46
DOIs
Publication statusPublished - Nov 21 2013
Externally publishedYes

Fingerprint

solar energy conversion
Bismuth
Photocatalysis
Nanorods
Energy conversion
Solar energy
bismuth
Catalysis
nanorods
catalysis
Infrared radiation
Fluorspar
solar energy
fluorite
Oxygen vacancies
Ionic conductivity
spectral sensitivity
Temperature
ion currents
energy

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Bismuth-induced integration of solar energy conversion with synergistic low-temperature catalysis in Ce1-xBixO2-δ nanorods. / Jiang, Dong; Wang, Wenzhong; Gao, Erping; Zhang, Ling; Sun, Songmei.

In: Journal of Physical Chemistry C, Vol. 117, No. 46, 21.11.2013, p. 24242-24249.

Research output: Contribution to journalArticle

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