Abstract
In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 70 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Feb 1 2014 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ 4 N]iron(II) . / Dai, Jing Wei; Li, Zhao Yang; Sato, Osamu.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 2, 01.02.2014.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ 4 N]iron(II)
AU - Dai, Jing Wei
AU - Li, Zhao Yang
AU - Sato, Osamu
PY - 2014/2/1
Y1 - 2014/2/1
N2 - In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.
AB - In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.
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U2 - 10.1107/S1600536813034818
DO - 10.1107/S1600536813034818
M3 - Article
VL - 70
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 2
ER -