Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4 N]iron(II)

Jing Wei Dai; Zhao Yang Li; Osamu Sato

doi:10.1107/S1600536813034818

Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ⁴ N]iron(II)

Jing Wei Dai, Zhao Yang Li, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title complex, [Fe(NCS)2(C18H18N4)], the Fe^II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å³, which are free of solvent molecules.

Original language	English
Pages (from-to)	m35
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	2
DOIs	https://doi.org/10.1107/S1600536813034818
Publication status	Published - Feb 2014

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4 N]iron(II)",

abstract = "In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3){\AA}] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9){\AA}3, which are free of solvent molecules.",

author = "Dai, {Jing Wei} and Li, {Zhao Yang} and Osamu Sato",

year = "2014",

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language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4 N]iron(II)

AU - Dai, Jing Wei

AU - Li, Zhao Yang

AU - Sato, Osamu

PY - 2014/2

Y1 - 2014/2

N2 - In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å3, which are free of solvent molecules.

AB - In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å3, which are free of solvent molecules.

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ER -

Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ⁴ N]iron(II)

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