TY - JOUR
T1 - Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4 N]iron(II)
AU - Dai, Jing Wei
AU - Li, Zhao Yang
AU - Sato, Osamu
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 2014/2
Y1 - 2014/2
N2 - In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å3, which are free of solvent molecules.
AB - In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å3, which are free of solvent molecules.
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U2 - 10.1107/S1600536813034818
DO - 10.1107/S1600536813034818
M3 - Article
AN - SCOPUS:84893710585
VL - 70
SP - m35
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 2
ER -