Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4 N]iron(II)

Jing Wei Dai, Zhao Yang Li, Osamu Sato

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1 Citation (Scopus)

Abstract

In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å3, which are free of solvent molecules.

Original languageEnglish
Pages (from-to)m35
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number2
DOIs
Publication statusPublished - Feb 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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