Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

Ken Sakai; Yuichi Uchida; Takashi Kajiwara; Tasuku Ito

doi:10.1107/S0108270103028841

Bis[tris(2,2′-bipyridine-κ ²N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

Ken Sakai, Yuichi Uchida, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title compound, [Ru^II(C₁₀H₈N ₂)₃]₂[Fe^III(CN) ₆]Cl·8H₂O, the [Ru(bpy)₃]²⁺ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)₆]^3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)₆]^3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

Original language	English
Pages (from-to)	m65-m68
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S0108270103028841
Publication status	Published - Feb 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry, Genetics and Molecular Biology(all)

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title = "Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate",

abstract = "In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) {\AA}], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) {\AA}] within the anionic sheets.",

author = "Ken Sakai and Yuichi Uchida and Takashi Kajiwara and Tasuku Ito",

year = "2004",

month = feb,

doi = "10.1107/S0108270103028841",

language = "English",

volume = "60",

pages = "m65--m68",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

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TY - JOUR

T1 - Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

AU - Sakai, Ken

AU - Uchida, Yuichi

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2004/2

Y1 - 2004/2

N2 - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

AB - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

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DO - 10.1107/S0108270103028841

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AN - SCOPUS:1642283695

VL - 60

SP - m65-m68

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 2

ER -

Bis[tris(2,2′-bipyridine-κ ²N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

Abstract

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