Abstract
In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.
| Original language | English |
|---|---|
| Pages (from-to) | m65-m68 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 60 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Feb 1 2004 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Biochemistry, Genetics and Molecular Biology(all)
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Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate. / Sakai, Ken; Uchida, Yuichi; Kajiwara, Takashi; Ito, Tasuku.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 60, No. 2, 01.02.2004, p. m65-m68.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate
AU - Sakai, Ken
AU - Uchida, Yuichi
AU - Kajiwara, Takashi
AU - Ito, Tasuku
PY - 2004/2/1
Y1 - 2004/2/1
N2 - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.
AB - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.
UR - http://www.scopus.com/inward/record.url?scp=1642283695&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=1642283695&partnerID=8YFLogxK
U2 - 10.1107/S0108270103028841
DO - 10.1107/S0108270103028841
M3 - Article
C2 - 14767116
AN - SCOPUS:1642283695
VL - 60
SP - m65-m68
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 2
ER -