Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

Ken Sakai, Yuichi Uchida, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

Original languageEnglish
Pages (from-to)m65-m68
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume60
Issue number2
DOIs
Publication statusPublished - Feb 1 2004
Externally publishedYes

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Ruthenium
Chlorides
Molecules
Water
Hydrogen
Ligands
Hydrogen Bonding
Anions
Cations
Hydrogen bonds
Atoms
Bistris
hexacyanoferrate III

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Bis[tris(2,2′-bipyridine-κ 2N,N′)-ruthenium(II)] hexacyanoferrate(III) chloride octahydrate. / Sakai, Ken; Uchida, Yuichi; Kajiwara, Takashi; Ito, Tasuku.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 60, No. 2, 01.02.2004, p. m65-m68.

Research output: Contribution to journalArticle

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abstract = "In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) {\AA}], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) {\AA}] within the anionic sheets.",
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AU - Ito, Tasuku

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N2 - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

AB - In the title compound, [RuII(C10H8N 2)3]2[FeIII(CN) 6]Cl·8H2O, the [Ru(bpy)3]2+ (bpy is 2,2′-bipyridine) cations and water molecules afford intriguing microporous honeycomb layers, while the [Fe(CN)6]3- anions and the remainder of the water molecules form anionic sheets based on extensive hydrogen-bonding networks. The cationic and anionic layers alternate along the c axis. The Fe atom in [Fe(CN)6]3- lies on an inversion centre and the axial cyano ligands are hydrogen bonded to the water molecules encapsulated within the micropores [N ⋯ O = 2.788 (5) Å], giving an unusual inter-penetration between the cationic and anionic layers. On the other hand, the in-plane cyano ligands are relatively weakly hydrogen bonded to the water molecules [N ⋯ O = 2.855 (7) and 2.881 (8) Å] within the anionic sheets.

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