C-H Bond Functionalization Using Pd- And Au-Supported Catalysts with Mechanistic Insights of the Active Species

Tamao Ishida, Zhenzhong Zhang, Haruno Murayama, Eiji Yamamoto, Makoto Tokunaga

Research output: Contribution to journalArticlepeer-review

Abstract

The process of C-H functionalization has been extensively studied as a direct C-C bond-forming reaction with high atomic efficiency. Efforts have also been made on such reactions by using supported catalysts, which are superior in terms of catalyst separation from the reaction mixture and reusability. In this review, an overview of C-H functionalization reactions, especially those involving Pd- and Au-supported catalysts, is presented. In particular, we discuss reaction mechanisms, active species, leaching, reusability, etc. 1 Introduction 2 Types of Supported Metal Catalysts and Their Active Species 3 Modes of C-H Bond Activation 4 Oxidative C-H C-H Coupling of Aryl Compounds 5 C-H C-H Coupling Where One Side Is Aromatic 6 C-H Acylation of Aromatic Compounds and Related Reactions 7 Conclusion.

Original languageEnglish
Pages (from-to)3279-3289
Number of pages11
JournalSynthesis (Germany)
Volume53
Issue number18
DOIs
Publication statusPublished - Sep 16 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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