Cage-size control of guest vibration and thermal conductivity in Sr8 Ga16 Si30-x Gex

Koichiro Suekuni, M. A. Avila, K. Umeo, T. Takabatake

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

We present a systematic study of thermal conductivity, specific heat, electrical resistivity, thermopower, and x-ray diffraction measurements performed on single-crystalline samples of the pseudoquaternary type-I clathrate system Sr8 Ga16 Si30-x Gex, in the full range of 0≤x≤30. All the samples show metallic behavior with n -type majority carriers. However, the thermal conductivity and specific heat strongly depend on x. Upon increasing x from 0 to 30, the lattice parameter increases by 3%, from 10.446 to 10.726 Å, and the localized vibrational energies of the Sr guest ions in the tetrakaidecahedron (dodecahedron) cages decrease from 59 (120) K to 35 (90) K. Furthermore, the lattice thermal conductivity at low temperatures is largely suppressed. In fact, a crystalline peak found at 15 K for x=0 gradually decreases and disappears for x≥20, evolving into the anomalous glasslike behavior observed for x=30. It is found that the increase of the free space for the Sr guest motion directly correlates with a continuous transition from quasi-on-center harmonic vibration to off-center anharmonic vibration, with consequent increase in the coupling strength between the guest's low-energy modes and the cage's acoustic phonon modes.

Original languageEnglish
Article number195210
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume75
Issue number19
DOIs
Publication statusPublished - May 21 2007
Externally publishedYes

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Thermal conductivity
thermal conductivity
vibration
conductivity
Specific heat
specific heat
Crystalline materials
majority carriers
clathrates
Thermoelectric power
Lattice constants
lattice parameters
x ray diffraction
Diffraction
Acoustics
Ions
harmonics
X rays
heat
electrical resistivity

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Cage-size control of guest vibration and thermal conductivity in Sr8 Ga16 Si30-x Gex. / Suekuni, Koichiro; Avila, M. A.; Umeo, K.; Takabatake, T.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 75, No. 19, 195210, 21.05.2007.

Research output: Contribution to journalArticle

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