Calcination effect of borate-bearing hydroxyapatite on the mobility of borate

Keiko Sasaki, Kenta Toshiyuki, Binglin Guo, Keiko Ideta, Yoshikazu Hayashi, Tsuyoshi Hirajima, Jin Miyawaki

Research output: Contribution to journalArticle

Abstract

Discharge from accidental nuclear power plants includes boric acid, which is used as a neutron absorbent in nuclear reactors. Co-precipitation of borate with hydroxyapatite (HAp), using Ca(OH)2, is known to be an effectively fast method for stabilization of borate as well as coexisting radioactive nuclides. To reduce bulky volume of solid residues after co-precipitation, calcination is necessary to investigate the chemical stability of targets. Calcination at 850 °C resulted in the high crystalization of HAp with formation of xCaO·B2O3 as a by-phase in which x increased with a decrease in the borate contents. After calcination, the lattice parameter a of HAp showed a reentrant curve and c showed a convex curve with an increase in borate contents. A dissolution assay revealed that calcination sometimes increases the borate moiety and that the acceptable B contents in HAp are lower than 1.59 mmol/g-calcined HAp. These results imply that during calcination of HAp, some borate is excluded to form the by-phase xCaO·B2O3, which is relatively insoluble in water, but some other fractions might be additionally emitted from the amorphous phase to weakly bind the calcined products.

Original languageEnglish
Pages (from-to)90-97
Number of pages8
JournalJournal of Hazardous Materials
Volume344
DOIs
Publication statusPublished - Feb 15 2018

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Bearings (structural)
Borates
borate
Durapatite
Hydroxyapatite
Calcination
Coprecipitation
Nuclear Reactors
Nuclear Power Plants
Boric acid
Chemical stability
Neutrons
Nuclear reactors
nuclear power plant
Radioisotopes
Nuclear power plants
Lattice constants
effect
Assays
Dissolution

All Science Journal Classification (ASJC) codes

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

Cite this

Calcination effect of borate-bearing hydroxyapatite on the mobility of borate. / Sasaki, Keiko; Toshiyuki, Kenta; Guo, Binglin; Ideta, Keiko; Hayashi, Yoshikazu; Hirajima, Tsuyoshi; Miyawaki, Jin.

In: Journal of Hazardous Materials, Vol. 344, 15.02.2018, p. 90-97.

Research output: Contribution to journalArticle

Sasaki, Keiko ; Toshiyuki, Kenta ; Guo, Binglin ; Ideta, Keiko ; Hayashi, Yoshikazu ; Hirajima, Tsuyoshi ; Miyawaki, Jin. / Calcination effect of borate-bearing hydroxyapatite on the mobility of borate. In: Journal of Hazardous Materials. 2018 ; Vol. 344. pp. 90-97.
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