Calix[4]arene-Mediated Transport of Alkali Ions Across Synthetic Black Lipid Membranes (BLM)

Nobuo Kimizuka, Tatsuo Wakiyama, Akihiro Yanagi, Seiji Shinkai, Toyoki Kunitake

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The calix[4]arene-mediated transport of alkali ions across black lipid membranes (BLM) of synthetic amphiphiles was examined by the charge pulse relaxation technique. Double-chain amphiphiles with cationic, anionic and nonionic head groups formed stable BLM's, and the transport parameters for alkali ions were determined. The calix[4]arene derivative displayed an enhanced transport rate for Na+ ion across the synthetic BLM's, while the relative adsorption/desorption rate (β) of alkali ions was significantly affected by the surface charge of the BLM's.

Original languageEnglish
Pages (from-to)3681-3684
Number of pages4
JournalBulletin of the Chemical Society of Japan
Volume69
Issue number12
DOIs
Publication statusPublished - Jan 1 1996

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Alkalies
Membrane Lipids
Ions
Amphiphiles
Surface charge
Desorption
Derivatives
Adsorption
calix(4)arene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Calix[4]arene-Mediated Transport of Alkali Ions Across Synthetic Black Lipid Membranes (BLM). / Kimizuka, Nobuo; Wakiyama, Tatsuo; Yanagi, Akihiro; Shinkai, Seiji; Kunitake, Toyoki.

In: Bulletin of the Chemical Society of Japan, Vol. 69, No. 12, 01.01.1996, p. 3681-3684.

Research output: Contribution to journalArticle

Kimizuka, Nobuo ; Wakiyama, Tatsuo ; Yanagi, Akihiro ; Shinkai, Seiji ; Kunitake, Toyoki. / Calix[4]arene-Mediated Transport of Alkali Ions Across Synthetic Black Lipid Membranes (BLM). In: Bulletin of the Chemical Society of Japan. 1996 ; Vol. 69, No. 12. pp. 3681-3684.
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