Carbon black / PTFE composite hydrophobic gas diffusion layers for a water-absorbing porous electrolyte electrolysis cell

Yuki Terayama, Takamasa Haji, Shoichi Furukawa, Munemitsu Nomura, Masamichi Nishihara, Stephen Matthew Lyth, Yoshitsugu Sone, Hiroshige Matsumoto

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The characteristics of a water-absorbing porous electrolyte electrolysis cell, in which pressurized water is injected directly into the electrolyte layer, are investigated. High water support force is required for the gas diffusion layer (GDL) in this novel cell design, and therefore here we report a new type of hydrophobic GDL comprising an acetylene black (AB) and poly(tetrafluoroethylene) (PTFE) composite film. The method of preparation of the AB/PTFE slurry, film formation methods, and the AB/PTFE weight ratio were investigated and optimized. The ball-milling and transfer method were suitable for preparing uniform AB/PTFE slurry and successfully covering AB/PTFE film without any cracks on micro-porous layer coated carbon paper, respectively. An investigation about different PTFE weight ratios against AB from 0.1 to 6 showed a serious trade-off character between electrical resistance R, gas permeability V′ and water support force Plim. The 1/2.5 of AB/PTFE weight ratio was most optimal, which showed to have most equivalent R (2.5 Ω cm−2), V′(136 mL atm−1 cm−2 min−1), and Plim (0.25 MPa). We also confirmed that fabricated GDL with optimal condition was worked as the blocking layer against water injected through electrolyte layer and pressurized by nitrogen gas, and as gas-permeation layer for generated hydrogen gas in water electrolysis test.

Original languageEnglish
Pages (from-to)2018-2025
Number of pages8
JournalInternational Journal of Hydrogen Energy
DOIs
Publication statusPublished - Jan 25 2018

Fingerprint

gaseous diffusion
Diffusion in gases
polytetrafluoroethylene
Acetylene
electrolysis
Carbon black
Polytetrafluoroethylenes
Electrolysis
acetylene
Electrolytes
electrolytes
composite materials
carbon
Composite materials
cells
water
Water
gases
Gases
Acoustic impedance

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Carbon black / PTFE composite hydrophobic gas diffusion layers for a water-absorbing porous electrolyte electrolysis cell. / Terayama, Yuki; Haji, Takamasa; Furukawa, Shoichi; Nomura, Munemitsu; Nishihara, Masamichi; Lyth, Stephen Matthew; Sone, Yoshitsugu; Matsumoto, Hiroshige.

In: International Journal of Hydrogen Energy, 25.01.2018, p. 2018-2025.

Research output: Contribution to journalArticle

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