Carbon nanotube adsorptive materials derived from acid degradable poly(acetals)

Andrew Mark Spring; Leandro A. Estrada; Svetlana V. Vasilyeva; Andrew G. Rinzler; John R. Reynolds

doi:10.1021/ma500009s

Carbon nanotube adsorptive materials derived from acid degradable poly(acetals)

Andrew Mark Spring, Leandro A. Estrada, Svetlana V. Vasilyeva, Andrew G. Rinzler, John R. Reynolds

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

In this paper, we report the synthesis and characterization of a well-controlled and acid degradable poly(acetal) which can adsorb strongly to the surface of carbon nanotubes (CNTs). These polymers, generated via acyclic diene metathesis (ADMET), incorporate pendant pyrene groups that are well-known to associate strongly to CNTs by noncovalent interactions. Films and solutions of the polymer were degraded through the controlled addition of aqueous hydrochloric acid in ethanol. The polymer's ability to adsorb to and be removed from a CNT film was also evaluated.

Original language	English
Pages (from-to)	2556-2560
Number of pages	5
Journal	Macromolecules
Volume	47
Issue number	8
DOIs	https://doi.org/10.1021/ma500009s
Publication status	Published - Apr 22 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry
Materials Chemistry
Polymers and Plastics
Inorganic Chemistry

Access to Document

10.1021/ma500009s

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AU - Spring, Andrew Mark

AU - Estrada, Leandro A.

AU - Vasilyeva, Svetlana V.

AU - Rinzler, Andrew G.

AU - Reynolds, John R.

PY - 2014/4/22

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AB - In this paper, we report the synthesis and characterization of a well-controlled and acid degradable poly(acetal) which can adsorb strongly to the surface of carbon nanotubes (CNTs). These polymers, generated via acyclic diene metathesis (ADMET), incorporate pendant pyrene groups that are well-known to associate strongly to CNTs by noncovalent interactions. Films and solutions of the polymer were degraded through the controlled addition of aqueous hydrochloric acid in ethanol. The polymer's ability to adsorb to and be removed from a CNT film was also evaluated.

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