Carbon-neutral energy cycles using alcohols

Takashi Fukushima, Sho Kitano, Shinichi Hata, Miho Yamauchi

    Research output: Contribution to journalArticlepeer-review

    10 Citations (Scopus)

    Abstract

    We demonstrated carbon-neutral (CN) energy circulation using glycolic acid (GC)/oxalic acid (OX) redox couple. Here, we report fundamental studies on both catalyst search for power generation process, i.e. GC oxidation, and elemental steps for fuel generation process, i.e. OX reduction, in CN cycle. The catalytic activity test on various transition metals revealed that Rh, Pd, Ir, and Pt have preferable features as a catalyst for electrochemical oxidation of GC. A carbon-supported Pt catalyst in alkaline conditions exhibited higher activity, durability, and product selectivity for electrooxidation of GC rather than those in acidic media. The kinetic study on OX reduction clearly indicated that OX reduction undergoes successive two-electron reductions to form GC. Furthermore, application of TiO2 catalysts with large specific area for electrochemical reduction of OX facilitates the selective formation of GC.

    Original languageEnglish
    Pages (from-to)142-152
    Number of pages11
    JournalScience and Technology of Advanced Materials
    Volume19
    Issue number1
    DOIs
    Publication statusPublished - Dec 31 2018

    All Science Journal Classification (ASJC) codes

    • Materials Science(all)

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