Carbon-skeleton rearrangement of an amino acid derivative as mediated by hydrophobic vitamin B12 covalently bound to a lipid species in a bilayer membrane

Yukito Murakami, Yoshio Hisaeda, Akihiro Ogawa, Teruhisa Ohno

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    Diethyl 2-acetylamino-2-methylpropanedioate co-ordinated to a hydrophobic vitamin B12 covalently bound to a peptide lipid underwent a carbon-skeleton rearrangement to afford diethyl 2-acetylaminobutanedioate in the single-walled vesicle of N,N-bis(hexadecyl)-Nα-(6-sulfohexanoyl)-L- alaninamide under photolysis conditions.

    Original languageEnglish
    Pages (from-to)189-191
    Number of pages3
    JournalJournal of the Chemical Society, Perkin Transactions 2
    Issue number2
    DOIs
    Publication statusPublished - 1995

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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